hydrogen; palladium on activated charcoal in ethanol Ambient temperature;

2: H2 / Pd-C / ethanol / Ambient temperature View Scheme

1: With C18H36N2O6*K(1+)*(18)FK in dimethyl sulfoxide T=75 - 85°C; 2: in water T=20°C;

lithium aluminium tetrahydride in diethylene glycol dimethyl ether T=110 - 115°C;

copper in acetonitrile T=60°C; 9 h; Inert atmosphere;

1.1: sodium hydride; 1H-imidazole / tetrahydrofuran; mineral oil / 0.5 h / 0 - 20 °C / |Inert atmosphere 1.2: 20 °C / |Inert atmosphere 1.3: 20 °C / |Inert atmosphere 2.1: copper / acetonitrile / 9 h / 60 °C / |Inert atmosphere View Scheme

1.1: triphenylphosphine / N,N-dimethyl-formamide 2.1: C18H36N2O6*K(1+)*(18)FK / dimethyl sulfoxide / 75 - 85 °C 2.2: 20 °C View Scheme

1: (trifluoromethyl)-trimethylsilane With copper(l) iodide; cesium fluoride in acetonitrile T=20°C; 0.5 h; Inert atmosphere; 2: With [Cu(MeCN)]4*CF3SO3 in acetonitrile T=20°C; 0.0166667 h; Inert atmosphere; 3: O-(4-fluorobenzyl)-S-methyl dithiocarbonate in acetonitrile T=20°C; 0.0333333 h; Inert atmosphereSonication; Kinetics;