反应条件
1: thionyl chloride / 1 h / 50 °C
2: 1.) triethylamine; 2.) 20percent HCl / 1.) chloroform, 35 deg C, 5 h; 2.) chloroform, reflux, 5 h
3: sodium hydroxide / ethanol / 1 h / Heating
4: 1.) hydrazine hydrate; 2.) potassium hydroxide / 1.) triethanolamine, 130 deg C; reflux, 4 h; 2.) triethanolamine, 200 deg C, 9 h
5: thionyl chloride / 1 h / 50 °C
6: 1.) triethylamine; 2.) 20percent HCl / 1.) chloroform, 35 deg C, 5 h; 2.) chloroform, reflux, 5 h
7: sodium hydroxide / ethanol / 1 h / Heating
8: 1.) hydrazine hydrate; 2.) potassium hydroxide / 1.) triethanolamine, 130 deg C; reflux, 4 h; 2.) triethanolamine, 200 deg C, 9 h
9: thionyl chloride / 1 h / 50 °C
View Scheme
参考文献
Ashikaga; Ito; Yamamoto; Nishijima
Journal of the American Chemical Society, 1988 , vol. 110, # 1 p. 198 - 204
