2-(溴甲基)六氟丙烷-2-醇合成路线 （共 8 条）
反应条件
P=0.05 Torr; laser photolysis-laser induced fluorescence (LP-LIF) techniqueneat (no solvent, gas phase); Quantum yieldMechanism;
参考文献
Indulkar, Yogesh N.; Upadhyaya, Hari P.; Kumar, Awadhesh; Waghmode, Suresh B.; Naik, Prakash D.
Journal of Photochemistry and Photobiology A: Chemistry, 2011 , vol. 222, # 1 p. 210 - 219
反应条件
P=0.05 Torr; laser photolysis-laser induced fluorescence (LP-LIF) techniqueneat (no solvent, gas phase); Quantum yieldMechanism;
参考文献
Indulkar, Yogesh N.; Upadhyaya, Hari P.; Kumar, Awadhesh; Waghmode, Suresh B.; Naik, Prakash D.
Journal of Photochemistry and Photobiology A: Chemistry, 2011 , vol. 222, # 1 p. 210 - 219
反应条件
1: 1,1-bis(trifluoromethyl)-2-bromoethanol With n-butyllithium in diethyl ether; hexane T=-78°C; 2: benzaldehyde in diethyl ether; hexane T=-78 - -10°C; 2 h;
参考文献
Grushin, Vladimir V.; Marshall, William J.; Halliday, Gary A.; Davidson, Fredric; Petrov, Viacheslav A.
Journal of Fluorine Chemistry, 2002 , vol. 117, # 2 p. 121 - 129
反应条件
1: 1,1-bis(trifluoromethyl)-2-bromoethanol With n-butyllithium in diethyl ether; hexane T=-78°C; 2: acetaldehyde in diethyl ether; hexane T=-78 - -10°C; 2 h;
参考文献
Grushin, Vladimir V.; Marshall, William J.; Halliday, Gary A.; Davidson, Fredric; Petrov, Viacheslav A.
Journal of Fluorine Chemistry, 2002 , vol. 117, # 2 p. 121 - 129
反应条件
hydrogen bromide
3 h; Heating;
参考文献
Grushin, Vladimir V.; Marshall, William J.; Halliday, Gary A.; Davidson, Fredric; Petrov, Viacheslav A.
Journal of Fluorine Chemistry, 2002 , vol. 117, # 2 p. 121 - 129
反应条件
1: 1,1-bis(trifluoromethyl)-2-bromoethanol With n-butyllithium in diethyl ether; hexane
T=-78°C;
2: chloro-diphenylphosphine in diethyl ether; hexane
T=-78 - 20°C;
参考文献
Grushin, Vladimir V.; Marshall, William J.; Halliday, Gary A.; Davidson, Fredric; Petrov, Viacheslav A.
Journal of Fluorine Chemistry, 2002 , vol. 117, # 2 p. 121 - 129
反应条件
P=0.05 Torr; laser photolysis-laser induced fluorescence (LP-LIF) techniqueneat (no solvent, gas phase); Quantum yieldMechanism;
参考文献
Indulkar, Yogesh N.; Upadhyaya, Hari P.; Kumar, Awadhesh; Waghmode, Suresh B.; Naik, Prakash D.
Journal of Photochemistry and Photobiology A: Chemistry, 2011 , vol. 222, # 1 p. 210 - 219
反应条件
1: 1,1-bis(trifluoromethyl)-2-bromoethanol With n-butyllithium in diethyl ether; hexane
T=-78°C;
2: 3,3,3-trifluoro-2-(trifluoromethyl)-1,2-propenoxide in diethyl ether; hexane
T=-78 - -10°C; 2 h;
参考文献
Grushin, Vladimir V.; Marshall, William J.; Halliday, Gary A.; Davidson, Fredric; Petrov, Viacheslav A.
Journal of Fluorine Chemistry, 2002 , vol. 117, # 2 p. 121 - 129
