N2-甲基-2,3-吡啶二胺合成路线 （共 19 条）
反应条件
hydrazine; palladium 10 on activated carbon in ethylene glycol dimethyl ether T=40°C; 4 h; Heating / reflux;
参考文献
PFIZER PRODUCTS INC.
Patent: WO2008/12622 A2, 2008 ;
Location in patent: Page/Page column 57 ;
WO 2008/012622 A2
反应条件
hydrogen; palladium 10 on activated carbon in ethanol T=20°C;
参考文献
TANIGUCHI, Takahiko; YOSHIKAWA, Masato; MIURA, Kasei; HASUI, Tomoaki; HONDA, Eiji; IMAMURA, Keisuke; KAMATA, Makoto; KAMISAKI, Haruhi; QUINN, John F.; RAKER, Joseph; CAMARA, Fatoumata; WANG, Yi
Patent: US2011/319394 A1, 2011 ;
Location in patent: Page/Page column 78 ;
反应条件
sodium chloride; hydrazine in ethanol; ethyl acetate
参考文献
Universal Display Corporation
Patent: US2012/228583 A1, 2012 ;
反应条件
copper(II) sulfate in water T=170°C; Sandmeyer reaction; 24 h;
参考文献
Chrisman; Knize; Tanga
Journal of Heterocyclic Chemistry, 2008 , vol. 45, # 6 p. 1641 - 1649
反应条件
lithium aluminium tetrahydride in tetrahydrofuran 0.5 h; Heating;
参考文献
Zecchini; Torrini; Paradisi
Journal of Heterocyclic Chemistry, 1985 , vol. 22, # 2 p. 313 - 318
反应条件
1: NaOAc / 80 °C 2: H2 / Pd/C / ethanol / 2585.74 Torr View Scheme
参考文献
Dudash Jr., Joseph; Zhang, Yongzheng; Moore, John B.; Look, Richard; Liang, Yin; Beavers, Mary Pat; Conway, Bruce R.; Rybczynski, Philip J.; Demarest, Keith T.
Bioorganic and Medicinal Chemistry Letters, 2005 , vol. 15, # 21 p. 4790 - 4793
反应条件
1: 60 percent / pyridine / tetrahydrofuran / 0 deg C, 15 min, then room temperature, 3 h 2: 80 percent / pyridine / tetrahydrofuran / 2 h / 0 °C 3: 100 percent / H2 / 5percent Pd/alumina / CH2Cl2 / 3 h 4: 91 percent / LiAlH4 / tetrahydrofuran / 0.5 h / Heating View Scheme
参考文献
Zecchini; Torrini; Paradisi
Journal of Heterocyclic Chemistry, 1985 , vol. 22, # 2 p. 313 - 318
反应条件
1: iron; acetic acid 2: CuSO4 View Scheme
参考文献
TANIGUCHI, Takahiko; YOSHIKAWA, Masato; MIURA, Kasei; HASUI, Tomoaki; HONDA, Eiji; IMAMURA, Keisuke; KAMATA, Makoto; KAMISAKI, Haruhi; QUINN, John F.; RAKER, Joseph; CAMARA, Fatoumata; WANG, Yi
Patent: US2011/319394 A1, 2011 ;
反应条件
1: 80 percent / pyridine / tetrahydrofuran / 2 h / 0 °C 2: 100 percent / H2 / 5percent Pd/alumina / CH2Cl2 / 3 h 3: 91 percent / LiAlH4 / tetrahydrofuran / 0.5 h / Heating View Scheme
参考文献
Zecchini; Torrini; Paradisi
Journal of Heterocyclic Chemistry, 1985 , vol. 22, # 2 p. 313 - 318
反应条件
1: 100 percent / H2 / 5percent Pd/alumina / CH2Cl2 / 3 h 2: 91 percent / LiAlH4 / tetrahydrofuran / 0.5 h / Heating View Scheme
参考文献
Zecchini; Torrini; Paradisi
Journal of Heterocyclic Chemistry, 1985 , vol. 22, # 2 p. 313 - 318
