(η5-C5H5)Mo(CO)3H in N-dodecane T=343 - 448°C; hydrogen abstraction; Kinetics;

1: 1) n-BuLi, N-isopropylcyclohexylamine / 1) THF, -70 deg C, 1 h, 2) THF, HMPA, r.t., overnight 2: 20percent aq. NaOH / methanol / 2 h / Heating 3: 1) diphenylphosphorazidate, Et3N, 2) 15percent HCl, AcOH / 1) benzene, a) 1 h, b) r.t., 1 h, c) reflux, 3 h, 2) r.t., overnight 4: 60 percent / SO2Cl2, Et3N / diethyl ether / a) -70 deg C, 2 h, b) -20 deg C, overnight 5: 1) NaH, 2) tert-butyl hypochlorite / 1) hexane, r.t., 3 h, 2) hexane, r.t., overnight 6: 26 percent / diethyl ether / 6 h / 23 °C / Irradiation; variation of concentration; addition of Ph2PH; addition of Mg-powder, activated by various methods View Scheme

1: 1) diphenylphosphorazidate, Et3N, 2) 15percent HCl, AcOH / 1) benzene, a) 1 h, b) r.t., 1 h, c) reflux, 3 h, 2) r.t., overnight 2: 60 percent / SO2Cl2, Et3N / diethyl ether / a) -70 deg C, 2 h, b) -20 deg C, overnight 3: 1) NaH, 2) tert-butyl hypochlorite / 1) hexane, r.t., 3 h, 2) hexane, r.t., overnight 4: 26 percent / diethyl ether / 6 h / 23 °C / Irradiation; variation of concentration; addition of Ph2PH; addition of Mg-powder, activated by various methods View Scheme

in tetrahydrofuran T=8°C; 72 h; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;

1: 29 percent / SOCl2 / pyridine / -17 °C 2: 50 percent Chromat. / Bu3SnH, azobisisobutyronitrile (AIBN) / benzene / 8 h / 80 °C View Scheme

1: Mg 2: 29 percent / SOCl2 / pyridine / -17 °C 3: 50 percent Chromat. / Bu3SnH, azobisisobutyronitrile (AIBN) / benzene / 8 h / 80 °C View Scheme

benzophenone; ethylmagnesium bromide 1.) ether, 8 h, 2.) n-butyl ether, 6 h; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;

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暂无反应条件数据

di-tert-butyl peroxide; tri-n-butylgermane in various solvent(s) T=-103.1°C; Irradiationvar. temp.; Rate constant;