十二碳-11-烯-2-酮合成路线 （共 33 条）
反应条件
bis(trimethylsilyl)-peroxide; tin(IV) chloride in tetrachloromethane T=25°C; 9 h;
参考文献
Matsubara; Takai; Nozaki
Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 7 p. 2029 - 2032
反应条件
dipyridinium dichromate in dichloromethane
T=20°C; 3 h;
参考文献
Qin, Xiangdong; Tzvetkov, Tochko; Liu, Xin; Lee, Dong-Chan; Yu, Luping; Jacobs, Dennis C.
Journal of the American Chemical Society, 2004 , vol. 126, # 41 p. 13232 - 13233
反应条件
sodium tungstate; dihydrogen peroxide in water
T=90°C; 3 h;
参考文献
Sato, Kazuhiko; Aoki, Masao; Takagi, Junko; Noyori, Ryoji
Journal of the American Chemical Society, 1997 , vol. 119, # 50 p. 12386 - 12387
反应条件
silver hexafluoroantimonate; water in methanol
T=75°C; 24 h; chemoselective reaction;
参考文献
Corominas, Albert; Montana, Angel M.
Synthetic Communications, 2013 , vol. 43, # 15 p. 2062 - 2072
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
T=25°C; 4 h;
参考文献
Wakamatsu, Kuni; Okuda, Yasuhiro; Oshima, Koichiro; Nozaki, Hitosi
Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 8 p. 2425 - 2426
反应条件
borane-THF; cyclohexene in tetrahydrofuran
1 h; Ambient temperature;
参考文献
Kabalka, George W.; Yu, Su; Li, Nan-Sheng
Canadian Journal of Chemistry, 1998 , vol. 76, # 6 p. 800 - 805
反应条件
chromium dichloride in tetrahydrofuran
T=25°C; Substitution; 24 h;
参考文献
Takai, Kazuhiko; Hikasa, Shintaro; Ichiguchi, Tetsuya; Sumino, Naoki
Synlett, 1999 , # 11 p. 1769 - 1771
反应条件
1: 62 percent / tetrahydrofuran; diethyl ether / 2 h / 0 - 20 °C
2: 84 percent / pyridinium dichromate / CH2Cl2 / 3 h / 20 °C
View Scheme
参考文献
Qin, Xiangdong; Tzvetkov, Tochko; Liu, Xin; Lee, Dong-Chan; Yu, Luping; Jacobs, Dennis C.
Journal of the American Chemical Society, 2004 , vol. 126, # 41 p. 13232 - 13233
反应条件
1: 89 percent / pyridinium chlorochromate / CH2Cl2 / 5 h / 20 °C
2: 62 percent / tetrahydrofuran; diethyl ether / 2 h / 0 - 20 °C
3: 84 percent / pyridinium dichromate / CH2Cl2 / 3 h / 20 °C
View Scheme
参考文献
Qin, Xiangdong; Tzvetkov, Tochko; Liu, Xin; Lee, Dong-Chan; Yu, Luping; Jacobs, Dennis C.
Journal of the American Chemical Society, 2004 , vol. 126, # 41 p. 13232 - 13233
参考文献
Kuraray Co., Ltd.
Patent: US4271320 A1, 1981 ;
