N,N-双-[(R)-1-苯基乙基]二苯并[d,f][1,3,2]二氧杂膦-6-胺合成路线 （共 4 条）
反应条件
1: bis(1-phenylethyl)amine With triethylamine; phosphorus trichoride in toluene
T=70°C; 6 h;
2: 2,2'-dihydroxy-1,1'-biphenyl With triethylamine in toluene
T=-78 - 20°C;
参考文献
Duran, Juan; Gulias, Moises; Castedo, Luis; Mascarenas, Jose L.
Organic Letters, 2005 , vol. 7, # 25 p. 5693 - 5696
反应条件
triethylamine in tetrahydrofuran; toluene
T=-78 - 25°C;
参考文献
Monti, Chiara; Gennari, Cesare; Piarulli, Umberto; De Vries, Johannes G.; De Vries, Andre H. M.; Lefort, Laurent
Chemistry - A European Journal, 2005 , vol. 11, # 22 p. 6701 - 6717
反应条件
1: PCl3; triethylamine / toluene / 6 h / 70 °C
2: triethylamine / tetrahydrofuran; toluene / -78 - 20 °C
View Scheme
参考文献
Monti, Chiara; Gennari, Cesare; Piarulli, Umberto
Chemistry - A European Journal, 2007 , vol. 13, # 5 p. 1547 - 1558
参考文献
Smith, Craig R.; Hwan, Jung Lim; Zhang, Aibin; RajanBabu
Synthesis, 2009 , # 12 art. no. C01309SS, p. 2089 - 2100
