反应条件
dichloro bis(acetonitrile) palladium(II) in N,N-dimethyl-formamide
to a soln. of complex in DMF at room temp. under Ar was added a norbornene soln. , then aryltin trichloride was added dropwise, the soln. was heated at 55°C for 2 h, cooled to room temp. treated with CH3MgI for 1 h; HCl was added, poured into water, extd. with ether, dried over Na2SO4, evapd., silica gel chromy., GPC (chloroform); 8percent mixt. of isomers (88:12);
参考文献
Fugami, Keigo; Kawata, Kentaro; Enokido, Tatsuki; Mishiba, Yukie; Hagiwara, Sachiko; Hirunuma, Yasuyuki; Koyama, Daisuke; Kameyama, Masayuki; Kosugi, Masanori
Journal of Organometallic Chemistry, 2000 , vol. 611, # 1-2 p. 433 - 444
