2,2-二氯-4’-甲基苯乙酮合成路线 （共 25 条）
反应条件
lt;Mn3O(OAc)6(OAc)(HOAc)gt;*5H2O; lithium chloride in acetic acid
0.3 h; Heating;
参考文献
Futami; Hishino; Kurosawa
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 11 p. 3567 - 3571
反应条件
in tetrahydrofuran
T=20°C; 1 h; Inert atmosphere; Reagent/catalyst;
参考文献
Essa, Ali H.; Lerrick, Reinner I.; Tuna, Floriana; Harrington, Ross W.; Clegg, William; Hall, Michael J.
Chemical Communications, 2013 , vol. 49, # 27 p. 2756 - 2758
参考文献
Ishihara Sangyo Kaisha, Ltd.
Patent: US5869683 A1, 1999 ;
反应条件
in tetrahydrofuran
T=20°C; 1 h; Inert atmosphere; Reagent/catalyst;
参考文献
Essa, Ali H.; Lerrick, Reinner I.; Tuna, Floriana; Harrington, Ross W.; Clegg, William; Hall, Michael J.
Chemical Communications, 2013 , vol. 49, # 27 p. 2756 - 2758
反应条件
1: N-chlorosuccinimide / toluene
2: aq. sulfuric acid / tetrahydrofuran / 4 h / Ambient temperature
View Scheme
参考文献
Barluenga, Jose; Tomas, Miguel; Lopez-Ortiz, J. Francisco; Gotor, Vicente
Synthesis, 1984 , # 11 p. 935 - 936
反应条件
1: 79 percent / N-chlorosuccinimide / toluene / 3 h / 50 °C
2: aq. sulfuric acid / tetrahydrofuran / 4 h / Ambient temperature
View Scheme
参考文献
Barluenga, Jose; Tomas, Miguel; Lopez-Ortiz, J. Francisco; Gotor, Vicente
Synthesis, 1984 , # 11 p. 935 - 936
反应条件
sulfuric acid in tetrahydrofuran
4 h; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Barluenga, Jose; Tomas, Miguel; Lopez-Ortiz, J. Francisco; Gotor, Vicente
Synthesis, 1984 , # 11 p. 935 - 936
反应条件
lt;Mn3O(OAc)6(OAc)(HOAc)gt;*5H2O; lithium chloride in acetic acid
0.3 h; Heating;
参考文献
Futami; Hishino; Kurosawa
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 11 p. 3567 - 3571
反应条件
1: AlCl3, aluminium chloride / dichloromethane / 1 h / 0 - 20 °C / |Inert atmosphere
2: PhMgI / tetrahydrofuran / 1 h / 20 °C / |Inert atmosphere
View Scheme
参考文献
Essa, Ali H.; Lerrick, Reinner I.; Tuna, Floriana; Harrington, Ross W.; Clegg, William; Hall, Michael J.
Chemical Communications, 2013 , vol. 49, # 27 p. 2756 - 2758
反应条件
piperidine; 1,3-Dichloro-5,5-dimethyl-2,4-imidazolidinedione
12 h; Molecular sieveReflux;
参考文献
Zhou, Bin; Chen, Zizhan; Zheng, Zubiao; Han, Bingbing; Zou, Xinzhuo
Synthetic Communications, 2012 , vol. 42, # 10 p. 1445 - 1453
