反式-2-甲基-2-丁烯醛合成路线 （共 86 条）
反应条件
borane-THF in tetrahydrofuran T=0°C; 2 h;
参考文献
Rodriguez, Ana M.; Enriz, Ricardo D.; Santagata, Luis N.; Jauregui, Esteban A.; Pestchanker, Mauricio J.; Giordano, Oscar S.
Journal of Medicinal Chemistry, 1997 , vol. 40, # 12 p. 1827 - 1834
反应条件
C34H51NP2; hydrogen; palladium (II) 2,4-pentanedionate; toluene-4-sulfonic acid in tetrahydrofuran T=100°C; P=30003 Torr; 10 h; Schlenk techniqueAutoclaveInert atmosphere; stereoselective reaction;
参考文献
Fang, Xianjie; Zhang, Min; Jackstell, Ralf; Beller, Matthias
Angewandte Chemie - International Edition, 2013 , vol. 52, # 17 p. 4645 - 4649
反应条件
triphenyl phosphite; hydrogen; [rhodium(I)(carbonyl)2(acetylacetonate)] in toluene T=30°C; P=30002.4 Torr; 46 h; Title compound not separated from byproducts;
参考文献
Breit, Bernhard; Demel, Peter; Gebert, Antje
Chemical Communications, 2004 , # 1 p. 114 - 115
反应条件
N,N,N',N,-tetramethylethylenediamine; hydrogen; di-(1-adamantyl)-n-butylphosphine; palladium diacetate in toluene T=100°C; P=5625.56 Torr; 16 h;
参考文献
Brennfuehrer, Anne; Neumann, Helfried; Klaus, Stefan; Riermeier, Thomas; Almena, Juan; Beller, Matthias
Tetrahedron, 2007 , vol. 63, # 27 p. 6252 - 6258
反应条件
N,N,N',N,-tetramethylethylenediamine; hydrogen; di-(1-adamantyl)-n-butylphosphine; palladium diacetate in toluene T=100°C; P=5625.56 Torr; 16 h;
参考文献
Brennfuehrer, Anne; Neumann, Helfried; Klaus, Stefan; Riermeier, Thomas; Almena, Juan; Beller, Matthias
Tetrahedron, 2007 , vol. 63, # 27 p. 6252 - 6258
反应条件
dipyridinium dichromate in dichloromethane Inert atmosphereMolecular sieve;
参考文献
Fotiadou, Anna D.; Zografos, Alexandros L.
Organic Letters, 2011 , vol. 13, # 17 p. 4592 - 4595
反应条件
HRh(PPh3)4 in benzene T=105°C; 3 h;
参考文献
Sato, Susumu; Matsuda, Isamu; Izumi, Yusuke
Journal of Organometallic Chemistry, 1989 , vol. 359, p. 255 - 266
反应条件
dichloro bis(acetonitrile) palladium(II) in dichloromethane 36 h; Ambient temperature;
参考文献
Takahashi, Mitsuru; Ishii, Norio; Suzuki, Hiroharu; Moro-Oka, Yoshihiko; Ikawa, Tsuneo
Chemistry Letters, 1981 , p. 1361 - 1362
反应条件
dicobalt octacarbonyl T=85°C; P=150012 Torr;
参考文献
Alper, Howard; Calet, Serge
Tetrahedron Letters, 1988 , vol. 29, # 15 p. 1763 - 1766
反应条件
1: lithium aluminium tetrahydride / diethyl ether / 20 °C / Inert atmosphere; Reflux 2: dipyridinium dichromate / dichloromethane / Inert atmosphere; Molecular sieve View Scheme
参考文献
Shimada, Naoyuki; Stewart, Craig; Bow, William F.; Jolit, Anais; Wong, Kahoano; Zhou, Zhe; Tius, Marcus A.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 23 p. 5727 - 5729
