1: copper(l) iodide; tetrabutylammomium bromide; palladium dichloride / dimethyl sulfoxide; N,N-dimethyl-formamide / 3 h / 120 °C / Inert atmosphere 2: pyridine hydrochloride / 1 h / 180 °C / Neat (no solvent); Inert atmosphere View Scheme
参考文献
McCutcheon, David C.; Paley, Miranda A.; Steinhardt, Rachel C.; Prescher, Jennifer A.
Journal of the American Chemical Society, 2012 , vol. 134, # 18 p. 7604 - 7607
McCutcheon, David C.; Paley, Miranda A.; Steinhardt, Rachel C.; Prescher, Jennifer A.
Journal of the American Chemical Society, 2012 , vol. 134, # 18 p. 7604 - 7607
1: copper(l) iodide; tetrabutylammomium bromide; palladium dichloride / dimethyl sulfoxide; N,N-dimethyl-formamide / 3 h / 120 °C / Inert atmosphere 2: pyridine hydrochloride / 1 h / 180 °C / Neat (no solvent); Inert atmosphere 3: potassium carbonate / methanol; water / 0.33 h / Inert atmosphere View Scheme
参考文献
McCutcheon, David C.; Paley, Miranda A.; Steinhardt, Rachel C.; Prescher, Jennifer A.
Journal of the American Chemical Society, 2012 , vol. 134, # 18 p. 7604 - 7607
1,8-diazabicyclo[5.4.0]undec-7-ene in dichloromethane
T=-5°C;
参考文献
McCutcheon, David C.; Paley, Miranda A.; Steinhardt, Rachel C.; Prescher, Jennifer A.
Journal of the American Chemical Society, 2012 , vol. 134, # 18 p. 7604 - 7607