2-羟基-6-(异丙基)-3-甲基环己-2-烯-1-酮合成路线 （共 26 条）
反应条件
copper diacetate; iodine in water; acetic acid 8 h; Ambient temperature;
参考文献
Horiuchi; Suzuki
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 9 p. 2919 - 2922
反应条件
bisacenaphthalenethiophene; oxygen in dichloromethane
T=-78°C; 0.666667 h; Irradiation;
参考文献
Wasserman, Harry H.; Ives, Jeffrey L.
Journal of Organic Chemistry, 1985 , vol. 50, # 19 p. 3573 - 3580
反应条件
1: With bromine in diethyl ether
T=-10°C; 8 h;
2: With sodium hydroxide in tetrahydrofuran
T=-60°C; 4 h;
参考文献
Schneider, David F; Viljoen, Murray S
Tetrahedron, 2002 , vol. 58, # 26 p. 5307 - 5315
反应条件
1: 87 percent / 36 h / 55 °C
2: 81 percent / O2, bisacenaphthalenethiophene (BANT) / CH2Cl2 / 0.67 h / -78 °C / Irradiation
View Scheme
参考文献
Wasserman, Harry H.; Ives, Jeffrey L.
Journal of Organic Chemistry, 1985 , vol. 50, # 19 p. 3573 - 3580
反应条件
n-butyllithium; diisopropylamine in tetrahydrofuran
1.) -10 deg C, 30 min 2.) 24 deg C, 19 h;
参考文献
Utaka, Masanori; Hojo, Makoto; Takeda, Akira
Chemistry Letters, 1984 , p. 445 - 448
反应条件
1.1: 91 percent / (COCl)2; DMSO; Et3N / CH2Cl2 / -60 - 20 °C
2.1: Br2 / diethyl ether / 8 h / -10 °C
2.2: 3 percent / aq. NaOH / tetrahydrofuran / 4 h / -60 °C
View Scheme
参考文献
Schneider, David F; Viljoen, Murray S
Tetrahedron, 2002 , vol. 58, # 26 p. 5307 - 5315
反应条件
sodium hydroxide
T=0°C; 6 h;
参考文献
Schneider, David F; Viljoen, Murray S
Tetrahedron, 2002 , vol. 58, # 26 p. 5307 - 5315
反应条件
1: LiI*2H2O / dimethylformamide
2: CuCl2, aq. AcOH
3: (i) Mor, aq. HCl, (ii) Zn, AcOH
View Scheme
参考文献
Ohashi,M. et al.
Bulletin of the Chemical Society of Japan, 1976 , vol. 49, p. 2292 - 2293
反应条件
methanol; sodium
1) room temperature, 18 h, 2) 50 deg C, 3 h;
参考文献
Schneider, David F.; Viljoen, Murray S.
Synthetic Communications, 1997 , vol. 27, # 19 p. 3349 - 3360
反应条件
sulfuric acid
T=60°C;
参考文献
Maignan,C.; Rouessac,F.
Bulletin de la Societe Chimique de France, 1976 , p. 550 - 554
