2-己烯-4-醇, CIS + TRANS合成路线 （共 34 条）
反应条件
formic acid Erhitzen des erhaltenen Gemisches von Mono-, Di- und Triformiat auf 220grad und Behandeln des Destillats mit siedender 50prozentiger Kalilauge;
参考文献
Delaby; Morel
Bulletin de la Societe Chimique de France, 1926 , vol. <4>39, p. 419
参考文献
Braude; Timmons
Journal of the Chemical Society, 1953 , p. 3144,3147
反应条件
T=-28 - -22°C; aehnlich verlaeuft die Umsetzung mit Propyl-, Allyl- und Phenylmagnesiumbromid;
参考文献
Stevens
Journal of the American Chemical Society, 1934 , vol. 56, p. 1425
Journal of the American Chemical Society, 1935 , vol. 57, p. 1112,1115
反应条件
MnTPPCl in benzene 2 h; Ambient temperaturevariations of pH, reagents, pO2, T; Product distributionMechanism;
参考文献
Fontecave, Marc; Mansuy, Daniel
Tetrahedron, 1984 , vol. 40, # 21 p. 4297 - 4312
反应条件
oxygen; anhydrous cobalt diacetate T=50°C; 72 h; possible cis-trans isomerisation and rearrangemets of hexenols under oxygen and nitrogen atmosphere; Product distribution;
参考文献
Frankel, Edwin N.; Garwood, Robert F.; Vinson, John R.; Weedon, Basil C. L.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , # 11 p. 2707 - 2714
反应条件
oxygen; rose bengal; triphenylphosphine multistep reaction: 1.) EtOH, 25 deg C, irradiation; other temperature (50 deg C); photosensitised oxidation of olefins, reduction of the hydroperoxides formed; Product distribution;
参考文献
Frankel, Edwin N.; Garwood, Robert F.; Vinson, John R.; Weedon, Basil C. L.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , # 11 p. 2715 - 2718
反应条件
oxygen; rose bengal; triphenylphosphine multistep reaction: 1.) EtOH, 25 deg C, irradiation; other temperature (50 deg C); photosensitised oxidation of olefins, reduction of the hydroperoxides formed; Product distribution;
参考文献
Frankel, Edwin N.; Garwood, Robert F.; Vinson, John R.; Weedon, Basil C. L.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , # 11 p. 2715 - 2718
反应条件
oxygen; anhydrous cobalt diacetate; triphenylphosphine multistep reaction: 1.) 25 deg C; other temperature (50 deg C); other catalysts; autooxidation of olefins, reduction of the hydroperoxides formed; Product distribution;
参考文献
Frankel, Edwin N.; Garwood, Robert F.; Vinson, John R.; Weedon, Basil C. L.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , # 11 p. 2707 - 2714
反应条件
oxygen; anhydrous cobalt diacetate; triphenylphosphine multistep reaction: 1.) 25 deg C; other temperature (50 deg C); other catalysts; autooxidation of olefins, reduction of the hydroperoxides formed, time dependence; Product distribution;
参考文献
Frankel, Edwin N.; Garwood, Robert F.; Vinson, John R.; Weedon, Basil C. L.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , # 11 p. 2707 - 2714
反应条件
oxygen; anhydrous cobalt diacetate; triphenylphosphine multistep reaction: 1.) 25 deg C; other temperature (50 deg C); other catalysts; autooxidation of olefins, reduction of the hydroperoxides formed; Product distribution;
参考文献
Frankel, Edwin N.; Garwood, Robert F.; Vinson, John R.; Weedon, Basil C. L.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , # 11 p. 2707 - 2714
