2-乙基环己-2,5-二烯-1,4-二酮合成路线 （共 20 条）
反应条件
K[VO(O2)2(2,2'-bipyridine)]*5H2O; dihydrogen peroxide; acetic acid in water
T=50°C; 4 h;
参考文献
Liu, Qiuyuan; Zhu, Liangfang; Li, Li; Guo, Bin; Hu, Xiaoke; Hu, Changwei
Journal of Molecular Catalysis A: Chemical, 2010 , vol. 331, # 1-2 p. 71 - 77
反应条件
Cu(NO3)2*3H2O; dihydrogen peroxide in acetonitrile
T=50°C; 4 h; aq. phosphate buffer; chemoselective reaction;
参考文献
Kamata, Keigo; Yamaura, Taiyo; Mizuno, Noritaka
Angewandte Chemie - International Edition, 2012 , vol. 51, # 29 p. 7275 - 7278
反应条件
sulfuric acid; acetic acid
Electrolysis.anschliessend Behandlung mit wss. Na2Cr2O7;
参考文献
Harman; Cason
Journal of Organic Chemistry, 1952 , vol. 17, p. 1058,1060
反应条件
sulfuric acid
bei der elektrolytischen Oxydation;
参考文献
Ono
Helvetica Chimica Acta, 1927 , vol. 10, p. 46,47, 51
反应条件
sodium dichromate; sulfuric acid
参考文献
Ladisch
Patent: US2840571 , 1956 ;
反应条件
[2,2']bipyridinyl; Balt;RuO3(OH)2gt;; trifluoroacetic acid in dichloromethane
T=20°C; 0.0333333 h; Product distribution;
参考文献
Lau, Tai-Chu; Mak, Chi-Keung
Journal of the Chemical Society, Chemical Communications, 1995 , # 9 p. 943 - 944
反应条件
T=20 - 30°C; bei der elektrolytischen Oxydation;
参考文献
Ono
Helvetica Chimica Acta, 1927 , vol. 10, p. 46,47, 51
反应条件
T=70°C; bei der elektrolytischen Oxydation;
参考文献
Ono
Helvetica Chimica Acta, 1927 , vol. 10, p. 46,47, 51
反应条件
1: 90 percent / benzene / 8 h / 110 °C
2: 84 percent / AcOH, Na2Cr2O7*2H2O, aq. H2SO4 / a) 80-90 deg C, 1 h, b) RT, 12 h
3: 90 percent / 30percent H2O2, aq. 30percent Na2CO3 / ethanol / 45 °C
4: 80 percent / 50percent aq. H2SO4 / 5 h
View Scheme
参考文献
Farina, F.; Fernandez, E.; Gimeno, V.; Valderrama, J. A.
Anales de Quimica, 1995 , vol. 91, # 3-4 p. 220 - 229
反应条件
1: 90 percent / benzene / 8 h / 110 °C
2: 84 percent / AcOH, Na2Cr2O7*2H2O, aq. H2SO4 / a) 80-90 deg C, 1 h, b) RT, 12 h
View Scheme
参考文献
Farina, F.; Fernandez, E.; Gimeno, V.; Valderrama, J. A.
Anales de Quimica, 1995 , vol. 91, # 3-4 p. 220 - 229
