7,7-二甲基-2-亚甲基-双环[2.2.1]庚烷合成路线 (共 12 条)
反应条件
6His-tagged Pseudomonas fluorescens PfO-1 Pfl_1841 2-methylenebornane synthase in pentane
T=30°C; pH=6.7; 12 h; aq. bufferEnzymatic reaction; Kinetics; Concentration;
参考文献
Chou, Wayne K.W.; Ikeda, Haruo; Cane, David E.
Tetrahedron, 2011 , vol. 67, # 35 p. 6627 - 6632
反应条件
HZSM-5-supported H4SiW12O40
T=160°C; P=760.051 Torr; 2 h;
参考文献
Szuecs-Balazs, Jozsef-Zsolt; Coros, Maria; Woiczechowski-Pop, Adrian; Blanita, Gabriela; Vlassa, Mircea
Central European Journal of Chemistry, 2012 , vol. 10, # 4 p. 1208 - 1217
反应条件
sodium hydrogencarbonate in pyridine
Yield given;
参考文献
Cervantes, Humberto; Khac, Duc Do; Fetizon, Marcel; Guir, Frederic; Beloeil, Jean-Claude; Lallemand, Jean-Yves
Tetrahedron, 1986 , vol. 42, # 13 p. 3491 - 3502
反应条件
1: pyridine / 24 h / Heating
2: aq. NaHCO3 / pyridine
View Scheme
参考文献
Cervantes, Humberto; Khac, Duc Do; Fetizon, Marcel; Guir, Frederic; Beloeil, Jean-Claude; Lallemand, Jean-Yves
Tetrahedron, 1986 , vol. 42, # 13 p. 3491 - 3502
参考文献
Kirmse, Wolfgang; Spaleck, Walter
Angewandte Chemie, 1981 , vol. 93, # 9 p. 791 - 792
反应条件
water in acetone
T=100°C; other temp; ΔH(excit.), ΔS(excit.); Rate constantKineticsThermodynamic data;
参考文献
Brown, Herbert C.; Ikegami, Shiro; Jagt, Dawid L. Vander
Journal of Organic Chemistry, 1985 , vol. 50, # 8 p. 1165 - 1171
反应条件
acetic acid; sodium nitrite
"Dl-fenchene" (l-α-fenchene);
参考文献
Wallach; Virck
Justus Liebigs Annalen der Chemie, 1908 , vol. 362, p. 177
反应条件
1: Py
2: AcOH, NaOAc
3: LiAlH4
4: LiAlH4
View Scheme
参考文献
Grison,C.; Bessiere-Chretien,Y.
Bulletin de la Societe Chimique de France, 1972 , p. 4570 - 4575
反应条件
clinoptilolite
T=156 - 165°C; P=760 Torr; 3 h; study of liquid-phase isomerization; activity and selectivity of natural catalyst dehydrated at 500 deg C with various time of calcination or without thermoevacuation; Product distributionMechanism;
参考文献
Allakhverdiev; Sokolova; Gunduz; Kul'kova
Russian Journal of Physical Chemistry A, 1998 , vol. 72, # 10 p. 1647 - 1650
反应条件
lanthanum; silica gel
T=49.85°C; 3 h; other reagents; Product distribution;
参考文献
Yamamoto, Takashi; Matsuyama, Takahiro; Tanaka, Tsunehiro; Funabiki, Takuzo; Yoshida, Satohiro
Physical Chemistry Chemical Physics, 1999 , vol. 1, # 11 p. 2841 - 2849