2-(苯磺酰甲基)苯甲醛合成路线 （共 13 条）
反应条件
diisobutylaluminium hydride in hexane; dichloromethane T=-78°C; 2 h;
参考文献
Orita, Akihiro; Hasegawa, Daiki; Nakano, Takehiko; Otera, Junzo
Chemistry - A European Journal, 2002 , vol. 8, # 9 p. 2000 - 2004
反应条件
pyridinium chlorochromate in dichloromethane T=20°C; 3 h;
参考文献
Patra, Asit; Ghorai, Sujit K.; De, Saroj R.; Mal, Dipakranjan
Synthesis, 2006 , # 15 p. 2556 - 2562
反应条件
1: 80 percent / NBS; AIBN / CCl4 / 2 h / 90 °C 2: 89 percent / dimethylformamide / 2 h / 80 °C 3: 78 percent / DIBAL-H / CH2Cl2; hexane / 2 h / -78 °C View Scheme
参考文献
Orita, Akihiro; Hasegawa, Daiki; Nakano, Takehiko; Otera, Junzo
Chemistry - A European Journal, 2002 , vol. 8, # 9 p. 2000 - 2004
反应条件
1: 89 percent / dimethylformamide / 2 h / 80 °C 2: 78 percent / DIBAL-H / CH2Cl2; hexane / 2 h / -78 °C View Scheme
参考文献
Orita, Akihiro; Hasegawa, Daiki; Nakano, Takehiko; Otera, Junzo
Chemistry - A European Journal, 2002 , vol. 8, # 9 p. 2000 - 2004
反应条件
1: dimethylformamide / 20 °C 2: 1.022 g / aq. NaOH; methanol / 20 °C 3: NaBH4; I2 / tetrahydrofuran / 0.33 h / 20 °C 4: 1.81 g / PCC / CH2Cl2 / 3 h / 20 °C View Scheme
参考文献
Patra, Asit; Ghorai, Sujit K.; De, Saroj R.; Mal, Dipakranjan
Synthesis, 2006 , # 15 p. 2556 - 2562
反应条件
1: 1.022 g / NBS; benzoyl peroxide / CCl4 / 1.5 h / Heating 2: dimethylformamide / 20 °C 3: 1.022 g / aq. NaOH; methanol / 20 °C 4: NaBH4; I2 / tetrahydrofuran / 0.33 h / 20 °C 5: 1.81 g / PCC / CH2Cl2 / 3 h / 20 °C View Scheme
参考文献
Patra, Asit; Ghorai, Sujit K.; De, Saroj R.; Mal, Dipakranjan
Synthesis, 2006 , # 15 p. 2556 - 2562
反应条件
1: NaBH4; I2 / tetrahydrofuran / 0.33 h / 20 °C 2: 1.81 g / PCC / CH2Cl2 / 3 h / 20 °C View Scheme
参考文献
Patra, Asit; Ghorai, Sujit K.; De, Saroj R.; Mal, Dipakranjan
Synthesis, 2006 , # 15 p. 2556 - 2562
反应条件
1: 1.022 g / aq. NaOH; methanol / 20 °C 2: NaBH4; I2 / tetrahydrofuran / 0.33 h / 20 °C 3: 1.81 g / PCC / CH2Cl2 / 3 h / 20 °C View Scheme
参考文献
Patra, Asit; Ghorai, Sujit K.; De, Saroj R.; Mal, Dipakranjan
Synthesis, 2006 , # 15 p. 2556 - 2562
反应条件
trimethylsilyl trifluoromethanesulfonate Etherification;
参考文献
Chemistry--A European Journal, , vol. 5, # 4 p. 1355 - 1363
反应条件
1.1: TMSOTf 2.1: BuLi / tetrahydrofuran; hexane / 1 h / -78 °C 2.2: tetrahydrofuran; hexane / 1 h / -78 °C 3.1: tetrahydrofuran; hexane / 2 h 4.1: t-BuOK / tetrahydrofuran; hexane / 3.67 h / 0 - 20 °C 5.1: 98 percent / p-TsOH; H2O / acetone / 16 h / 40 °C View Scheme
参考文献
Orita, Akihiro; Yoshioka, Naonori; Struwe, Petra; Braier, Arnold; Beckmann, Anke; Otera, Junzo
Chemistry--A European Journal, 1999 , vol. 5, # 4 p. 1355 - 1363
