1,2'-二萘胺(升华精制品)合成路线 （共 10 条）
反应条件
bis(1,5-cyclooctadiene)nickel (0); C{N(2,6-iPr2C6H3)CH}2 in tetrahydrofuran; 1,4-dioxane T=150°C; Kumada Cross-Coupling; 24 h; Inert atmosphere;
参考文献
Tadaoka, Hiroshi; Yamakawa, Tetsu
Tetrahedron Letters, 2012 , vol. 53, # 41 p. 5531 - 5534
反应条件
NiCl(1-naphthyl)(PPh3)2; sodium hydride; 1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride in 1,4-dioxane T=110°C; Inert atmosphere;
参考文献
Huang, Jin-Hua; Yang, Lian-Ming
Organic Letters, 2011 , vol. 13, # 14 p. 3750 - 3753
参考文献
DE14612 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 1, p. 412
反应条件
T=160°C; und anschliessend auf 210grad;
参考文献
Gazzetta Chimica Italiana, , vol. 54, p. 825
参考文献
DE14612 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 1, p. 412
反应条件
zinc(II) chloride T=220°C;
参考文献
Buu-Hoi
Journal of the Chemical Society, 1950 , p. 1146,1151
反应条件
1: With palladium diacetate in toluene 2: With tri-tert-butyl phosphine in toluene T=75°C; 1 h; 3: With sodium t-butanolate in tetrahydrofuran; toluene T=75 - 80°C; 3.5 h; Product distribution / selectivity;
参考文献
WO2006/11879 A1, ;
Page/Page column 15-16 ;
参考文献
Kehrmann et al.
Chemische Berichte, 1923 , vol. 56, p. 649
反应条件
(+/-)-2-methylbutyric anhydride; zinc(II) chloride T=270°C; 13 h; Yield given;
参考文献
Klemm, L.H.; Chiang, Eva; O'Bannon, Gerald W.
Journal of Heterocyclic Chemistry, 1992 , vol. 29, # 2 p. 571 - 574
反应条件
1: sodium acetate
2: alcohol; hydrochloric acid
View Scheme
参考文献
Matthes
Chemische Berichte, 1890 , vol. 23, p. 1333
