5-甲基-5-硝基己烷-2-酮合成路线 （共 12 条）
反应条件
1: Zn dust 3: <Ox(1-)> View Scheme
参考文献
Scott, Alan C.; Tedder, John M.; Walton, John C.; Mhatre, Sushila
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980 , p. 260 - 266
反应条件
Verkade’s superbase in various solvent(s)
T=20°C; Michael addition; 0.25 h;
参考文献
Kisanga, Philip B.; Ilankumaran, Palanichamy; Fetterly, Brandon M.; Verkade, John G.
Journal of Organic Chemistry, 2002 , vol. 67, # 11 p. 3555 - 3560
反应条件
ethyl acetate; bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine in various solvent(s)
T=85°C; 22 h;
参考文献
Aleksandrowicz, Piotr; Piotrowska, Hanna; Sas, Wojciech
Tetrahedron, 1982 , vol. 38, # 9 p. 1321 - 1327
反应条件
oxalic acid in nitromethane
T=60°C; 12 h;
参考文献
Miyake, Hideyoshi; Nakao, Yuichi; Sasaki, Mitsuru
Tetrahedron Letters, 2006 , vol. 47, # 35 p. 6247 - 6250
反应条件
ethyl acetate; bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine in methanol
T=60°C; 93 h;
参考文献
Aleksandrowicz, Piotr; Piotrowska, Hanna; Sas, Wojciech
Tetrahedron, 1982 , vol. 38, # 9 p. 1321 - 1327
反应条件
bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine in isopropyl alcohol
T=75°C; 8 h;
参考文献
Aleksandrowicz, Piotr; Piotrowska, Hanna; Sas, Wojciech
Tetrahedron, 1982 , vol. 38, # 9 p. 1321 - 1327
反应条件
bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine in methanol
T=65°C; 66 h;
参考文献
Aleksandrowicz, Piotr; Piotrowska, Hanna; Sas, Wojciech
Tetrahedron, 1982 , vol. 38, # 9 p. 1321 - 1327
参考文献
Gill et al.
Journal of the American Chemical Society, 1952 , vol. 74, p. 4923,4927
反应条件
(i) NaOH, NaOAc, H2O, MeOH, (ii) /BRN= 1754095/; Multistep reaction;
参考文献
Feuer,H.; Miller,R.
Journal of Organic Chemistry, 1961 , vol. 26, p. 1348 - 1357
反应条件
lithium aluminium tetrahydride in tetrahydrofuran
20 h; Ambient temperature;
参考文献
Sosnovsky; Paul
1983 , vol. 38, # 9 p. 1146 - 1155
