3-甲基-1-苯基-2-丁烯合成路线 （共 98 条）
反应条件
lithium diethylamide in N,N,N',N',N'',N''-hexamethylphosphoric triamide; diethyl ether
T=19°C; 20 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Babin, D.; Fourneron, J. D.; Harwood, L. M.; Julia, M.
Tetrahedron, 1981 , vol. 37, p. 325 - 332
反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine in hexane
T=19°C; 24 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Babin, D.; Fourneron, J. D.; Harwood, L. M.; Julia, M.
Tetrahedron, 1981 , vol. 37, p. 325 - 332
反应条件
iron(III) tris(dibenzoylmethane) in tetrahydrofuran
T=65°C; 6 h;
参考文献
Gai, Yonghua; Julia, Marc; Jean-Noe; Verpeaux
Bulletin de la Societe Chimique de France, 1996 , vol. 133, # 9 p. 805 - 816
反应条件
1: hydrogen bromide
2: folgend Behandlung des Reaktionsprodukts mit verd. Salzsaeure
View Scheme
参考文献
Claisen
Journal fuer Praktische Chemie (Leipzig), 1922 , vol. <2> 105, p. 72
Chemische Berichte, 1925 , vol. 58, p. 279 Anm. 15
反应条件
water; palladium diacetate; potassium carbonate in toluene
T=90°C; 3 h;
参考文献
Scrivanti, Alberto; Beghetto, Valentina; Bertoldini, Matteo; Matteoli, Ugo
European Journal of Organic Chemistry, 2012 , # 2 p. 264 - 268
反应条件
water; palladium diacetate; potassium carbonate in toluene
T=90°C; 3 h;
参考文献
Scrivanti, Alberto; Beghetto, Valentina; Bertoldini, Matteo; Matteoli, Ugo
European Journal of Organic Chemistry, 2012 , # 2 p. 264 - 268
反应条件
silver tetrafluoroborate
参考文献
Billups,W.E. et al.
Journal of the American Chemical Society, 1974 , vol. 96, # 6 p. 1979 - 1980
反应条件
1: 81 percent / n-BuLi / tetrahydrofuran / 1.) -78 deg C, 2.5 h, 2.) 25 deg C, 12 h
2: 46 percent / (Bu3Sn)2 / benzene / 18 h / Irradiation
View Scheme
参考文献
Van Dort; Fuchs
Journal of Organic Chemistry, 1997 , vol. 62, # 21 p. 7142 - 7147
反应条件
1: neat (no solvent) / 16 h / 120 °C
2: 1.) n-BuLi / 1.) THF, cyclohexane, reflux, 1 h, 2.) THF, reflux, 10 h
View Scheme
参考文献
Angelis, Yiannis S.; Orfanopoulos, Michael
Journal of Organic Chemistry, 1997 , vol. 62, # 17 p. 6083 - 6085
反应条件
Lawesson's reagent in toluene
0.5 h; Heating; Title compound not separated from byproducts;
参考文献
Nishio, Takehiko
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1993 , # 10 p. 1113 - 1118
