顺式-4-甲基-2-戊烯合成路线 （共 45 条）
反应条件
methanesulfonic acid; α,α'-bis(di-t-butylphosphino)-o-xylene; tris-(dibenzylideneacetone)dipalladium(0) T=20°C; P=760 Torr; 3 h;
参考文献
Rodriguez, Cristina Jimenez; Foster, Douglas F.; Eastham, Graham R.; Cole-Hamilton, David J.
Chemical Communications, 2004 , # 15 p. 1720 - 1721
参考文献
Nikishin,G.I. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1960 , vol. 30, # 7 p. 2148 - 2153,2124 - 2129
反应条件
hydrogen; cobalt T=120 - 160°C; P=73550.8 - 147102 Torr; Hydrieren des Reaktionsproduktes am gleichen Katalysator;
参考文献
Keulemans; Kwantes; van Bavel
Recueil des Travaux Chimiques des Pays-Bas, 1948 , vol. 67, p. 302
反应条件
Hydrierung der entstandenen Aldehyde an den gleichen Katalysatoren unter Druck; Product distribution;
参考文献
Keulemans; Kwantes; van Bavel
Recueil des Travaux Chimiques des Pays-Bas, 1948 , vol. 67, p. 302
反应条件
hydrogen; palladium(II) sulfide T=80°C; vapor phase reaction, atmospheric pressure, other temperatures, isomerization contribution, activation energy, other methylpentenes and 1-alkenes; benzene, toluene, xylene presence; KineticsRate constant;
参考文献
Matveeva, T.M.; Nekrasov, N.V.; Kostyukovskii, M.M.; Kiperman, S.L.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1984 , vol. 33, # 11 p. 2227 - 2232
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1984 , # 11 p. 2437 - 2442
反应条件
in dichloromethane Irradiation;
参考文献
Strub, Henri; Strehler, Christiane; Streith, Jacques
Chemische Berichte, 1987 , vol. 120, p. 355 - 364
反应条件
in dichloromethane Irradiationvariation of the cis/trans-ratio of the reactant, also irradiation with reactant cis-4-methyl-2-pentene in the presence of cyclohexane and α-methylstyrene; Product distribution;
参考文献
Strub, Henri; Strehler, Christiane; Streith, Jacques
Chemische Berichte, 1987 , vol. 120, p. 355 - 364
反应条件
1: iodine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 20 °C 2: dichloromethane; N,N-dimethyl-formamide / 12 h / 20 °C View Scheme
参考文献
Donohoe, Timothy J.; Kabeshov, Mikhail A.; Rathi, Akshat H.; Smith, Ian E. D.
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 5 p. 1093 - 1101
参考文献
Gorski
Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1910 , vol. 42, p. 1356
Chem. Zentralbl., 1911 , vol. 82, # I p. 635
反应条件
in toluene
T=10°C; 2 h;
参考文献
Sumitomo Chemical Company, Limited
Patent: US6388160 B1, 2002 ;
Location in patent: Page column 5-6 ;
