2-甲基-3-苯基环氧乙烷合成路线 （共 22 条）
反应条件
boron trifluoride diethyl etherate T=-78°C; 1 h; further reagents (chromyl nitrate, HNO3, ZnCl2); Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 105, # 8 p. 2368 - 2378
参考文献
Russian Chemical Bulletin, , vol. 44, # 5 p. 919 - 922
Izvestiya Akademi Nauk, Seriya Khimicheskaya, , # 5 p. 946 - 949
反应条件
KH2F3 in 1,2-dichloro-ethane T=80°C; 12 h; further epoxides; Product distribution;
参考文献
Journal of Fluorine Chemistry, , vol. 70, # 1 p. 1 - 4
参考文献
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 188, p. 713
Bulletin de la Societe Chimique de France, , vol. <4> 49, p. 1765,1775
参考文献
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 188, p. 713
Bulletin de la Societe Chimique de France, , vol. <4> 49, p. 1765,1775
参考文献
Weijers, Carel A. G. M.
Tetrahedron Asymmetry, 1997 , vol. 8, # 4 p. 639 - 647
反应条件
Amberlite IRA-400; borohydride form; copper(II) sulfate in methanol T=65°C; Reduction; 1 h;
参考文献
Sim, Tae Bo; Yoon, Nung Min
Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 5 p. 1101 - 1107
反应条件
Amberlite IRA-400; borohydride form; copper(II) sulfate in methanol T=20°C; Reduction; 3 h;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 70, # 5 p. 1101 - 1107
反应条件
1: With zinc trifluoromethanesulfonate
T=20°C; 1 h; Inert atmosphere;
2: With 1,1'-bis-(diphenylphosphino)ferrocene; tri-ruthenium(0)dodecacarbonyl; toluene-4-sulfonic acid in 1,4-dioxane
T=150°C; 22 h; Inert atmosphere; regioselective reaction;
参考文献
Pena-Lopez, Miguel; Neumann, Helfried; Beller, Matthias
Chemistry - A European Journal, 2014 , vol. 20, # 7 p. 1818 - 1824
反应条件
sodium hydroxide; methyl iodide; dicobalt octacarbonyl; N-hexadecyl-N,N,N-trimethylammonium bromide in benzene
P=760 Torr; Ambient temperature;
参考文献
Alper, Howard; Arzoumanian, Henri; Petrignani, Jean-Francois; Saldana-Maldonado, Manuel
Journal of the Chemical Society, Chemical Communications, 1985 , # 6 p. 340 - 341
