2,4,6,2',4',6'-六硝基联苯合成路线 （共 9 条）
反应条件
copper in nitrobenzene
0.15 h;
参考文献
Nelson; Adolph
Synthetic Communications, 1991 , vol. 21, # 2 p. 293 - 305
反应条件
copper; nitrobenzene
参考文献
Ullmann; Bielecki
Chemische Berichte, 1901 , vol. 34, p. 2176
反应条件
ortho-chlorotoluene; copper
T=150°C; 0.5 h;
参考文献
Bell, Anthony J.; Read, Roger W.
Australian Journal of Chemistry, 1987 , vol. 40, # 11 p. 1813 - 1829
反应条件
copper
T=150°C; 0.5 h;
参考文献
Bell, Anthony J.; Read, Roger W.
Australian Journal of Chemistry, 1987 , vol. 40, # 11 p. 1813 - 1829
反应条件
1: 61 percent / KNO3, 30percent oleum / 6 h / 125 °C
2: 88 percent / Cu / toluene / 1 h / 120 °C
3: 91 percent / 98percent H2SO4, HNO3 / 1.5 h / 90 °C
4: 95 percent / SOBr2, DMF / 1,2-dichloro-ethane / 2 h / Heating
5: Cu / nitrobenzene / 2 h / 180 °C
View Scheme
参考文献
Bellamy, Anthony J.; Hudson, P. Nick
Journal of Chemical Research, Miniprint, 1996 , # 4 p. 959 - 978
反应条件
1: 91 percent / PBr3 / toluene; dimethylformamide / 1 h / 75 °C
2: 88 percent / Cu / toluene / 1 h / 120 °C
3: 91 percent / 98percent H2SO4, HNO3 / 1.5 h / 90 °C
4: 95 percent / SOBr2, DMF / 1,2-dichloro-ethane / 2 h / Heating
5: Cu / nitrobenzene / 2 h / 180 °C
View Scheme
参考文献
Bellamy, Anthony J.; Hudson, P. Nick
Journal of Chemical Research, Miniprint, 1996 , # 4 p. 959 - 978
反应条件
sulfuric acid; nitric acid
T=160°C; 2 h; Further byproducts given;
参考文献
Adrievskii, A. M.; Poplavskii, A. N.; Dyumaev, K. M.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, p. 1195 - 1198
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 6 p. 1314 - 1317
反应条件
water-d2
1.) nitrobenzene, 12 min, irrad., 2.) nitrobenzene, acetone-d6, RT, overnight; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Nelson; Adolph
Synthetic Communications, 1991 , vol. 21, # 2 p. 293 - 305
反应条件
sulfuric acid; nitric acid
T=160°C; 2 h; various temperature; Product distribution;
参考文献
Adrievskii, A. M.; Poplavskii, A. N.; Dyumaev, K. M.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, p. 1195 - 1198
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 6 p. 1314 - 1317
