1: phenyl-magnesium chloride With AlCl3, aluminium chloride in tetrahydrofuran
T=20°C; 1 h;
2: c-heptyl-Cl With anhydrous iron chloride; bis(1,2-diphenylphosphino)benzene in tetrahydrofuran
T=80°C; 24 h; Product distribution / selectivity;
参考文献
Kyoto University
Patent: US2011/152523 A1, 2011 ;
Location in patent: Page/Page column 22 ;
anhydrous iron chloride in tetrahydrofuran
T=0°C; 0.666667 h; Inert atmosphere;
参考文献
Noda, Daisuke; Sunada, Yusuke; Hatakeyama, Takuji; Nakamura, Masaharu; Nagashima, Hideo
Journal of the American Chemical Society, 2009 , vol. 131, p. 6078 - 6079
1: phenyl-magnesium chloride With AlCl3, aluminium chloride in tetrahydrofuran
T=20°C; 1 h;
2: c-heptyl-Cl With anhydrous iron chloride; (3,5-tBu-SciOPP) in tetrahydrofuran
T=80°C; 24 h; Product distribution / selectivity;
参考文献
Kyoto University
Patent: US2011/152523 A1, 2011 ;
Location in patent: Page/Page column 22 ;
anhydrous iron chloride in tetrahydrofuran
T=-78°C; 0.5 h; Inert atmosphere;
参考文献
Noda, Daisuke; Sunada, Yusuke; Hatakeyama, Takuji; Nakamura, Masaharu; Nagashima, Hideo
Journal of the American Chemical Society, 2009 , vol. 131, p. 6078 - 6079
1: phenyl-magnesium chloride With AlCl3, aluminium chloride in tetrahydrofuran
T=0 - 20°C;
2: cycloheptyl bromide With anhydrous iron chloride in tetrahydrofuran
T=0 - 80°C;
参考文献
Kawamura, Shintaro; Ishizuka, Kentaro; Takaya, Hikaru; Nakamura, Masaharu
Chemical Communications, 2010 , vol. 46, # 33 p. 6054 - 6056
