2-(氯羰基)苯甲酸甲酯合成路线 （共 40 条）
反应条件
1: pyridine; hydrazine hydrate
2: aqueous H2SO4
3: 160 °C / weiteres Edukt Nitrobenzol.
View Scheme
参考文献
Drew; Hatt
Journal of the Chemical Society, 1937 , p. 16,25
反应条件
1.1: zinc / toluene / 20 °C
2.1: sodium hydroxide; water / methanol / 1 h / 20 °C
3.1: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; benzotriazol-1-ol / tetrahydrofuran / 0.5 h
3.2: 20 °C
4.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / methanol; tetrahydrofuran / 12 h / |Reflux
5.1: trifluoroacetic acid; methoxybenzene; sulfuric acid / 0.5 h / 90 °C
6.1: hydrogenchloride; water / acetonitrile / 10 h / |Reflux
View Scheme
参考文献
Feng, Cheng-Liang; Zhang, Shu-Guang; Chen, Jun-Qing; Cai, Jin; Ji, Min
Chinese Chemical Letters, 2013 , vol. 24, # 8 p. 767 - 769
反应条件
1: 85 percent / pyridine / CH2Cl2 / 24 h / 25 °C
2: 42 percent / 1 h / 700 °C / 0.05 Torr
View Scheme
参考文献
Baradarani, Mehdi M.; Khalafy, Jabbar; Prager, Rolf H.
Australian Journal of Chemistry, 1999 , vol. 52, # 8 p. 775 - 780
参考文献
Cook et al.
Journal of the Chemical Society, 1950 , p. 139,146
参考文献
Drew; Hatt
Journal of the Chemical Society, 1937 , p. 16,25
反应条件
1: pyridine; hydrazine hydrate
2: acetic acid
View Scheme
参考文献
Drew; Hatt
Journal of the Chemical Society, 1937 , p. 16,25
反应条件
1: diethyl ether
2: dil. H2SO4
View Scheme
参考文献
Chapyshev, S. V.; Kurkovskii, L. I.; Kartsev, V. G.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1987 , vol. 36, # 4 p. 765 - 770
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1987 , # 4 p. 837 - 842
反应条件
pyridine
T=100°C; 1 h;
参考文献
Meyer, Emerson; Joussef, Antonio C.; Gallardo, Hugo
Synthesis, 2003 , # 6 p. 899 - 905
反应条件
carbon disulfide; aluminium trichloride
参考文献
Dufraisse; Allais
Bulletin de la Societe Chimique de France, 1944 , vol. <5> 11, p. 531,534
反应条件
sodium tetrahydroborate; potassium carbonate in dichloromethane; water
T=0 - 15°C; chemoselective reaction;
参考文献
Rajan, Ramya; Badgujar, Sachin; Kaur, Kamaljit; Malpani, Yashwardhan; Kanjilal, Pranab R.
Synthetic Communications, 2010 , vol. 40, # 19 p. 2897 - 2907
