1,1-二甲基-2-亚甲基环丙烷合成路线 （共 12 条）
反应条件
bis(1,5-cyclooctadiene)nickel (0) T=50°C; 10 h; MechanismProduct distribution;
参考文献
Binger, Paul; Brinkmann, Axel; Wedemann,Petra
Chemische Berichte, 1983 , vol. 116, # 8 p. 2920 - 2930
反应条件
1: KOtBu / pentane
2: nBu3SnH
3: nBu3SnH
View Scheme
参考文献
Rahman,W.; Kuivila,H.G.
Journal of Organic Chemistry, 1966 , vol. 31, p. 772 - 776
反应条件
in benzene
(Ar); addn. of soln. of org. compd. in C6H6 to suspn. of Ni-complex in C6H6, stirring (20 h, 22°C); evapn. to dryness (vac.), pptn. on addn. of ether, filtration, washing (ether), drying (vac.);
参考文献
Isaeva, L. S.; Peganova, T. A.; Petrovskii, P. V.; Kravtsov, D. N.
Journal of Organometallic Chemistry, 1989 , vol. 376, p. 141 - 148
反应条件
potassium tert-butylate
参考文献
Arora,S.; Binger,P.
Synthesis, 1974 , p. 801 - 803
反应条件
potassium tert-butylate in dimethyl sulfoxide
参考文献
Formanovskii,A.A. et al.
Zhurnal Organicheskoi Khimii, 1977 , vol. 13, # 9 p. 1883 - 1887,1745 - 1749
反应条件
1: NaOMe / bis-(2-methoxy-ethyl) ether / 160 °C
2: KOtBu / dimethylsulfoxide
View Scheme
参考文献
Formanovskii,A.A. et al.
Zhurnal Organicheskoi Khimii, 1977 , vol. 13, # 9 p. 1883 - 1887,1745 - 1749
反应条件
diiodomethane; copper; zinc in diethyl ether
24 h; Heating;
参考文献
Battioni-Savignat,P. et al.
Bulletin de la Societe Chimique de France, 1967 , p. 3929 - 3930
反应条件
tri-n-butyl-tin hydride
参考文献
Rahman,W.; Kuivila,H.G.
Journal of Organic Chemistry, 1966 , vol. 31, p. 772 - 776
反应条件
diiodomethane; copper; zinc in diethyl ether
24 h; Heating;
参考文献
Battioni-Savignat,P. et al.
Bulletin de la Societe Chimique de France, 1967 , p. 3929 - 3930
反应条件
T=180°C; gas-phase thermolysis; Rate constant;
参考文献
LeFevre, Gerard N.; Crawford, Robert J.
Journal of the American Chemical Society, 1986 , vol. 108, # 5 p. 1019 - 1027
