in dichloromethane T=-30°C;

18-crown-6 ether; NOBF4 in acetonitrile T=-50 - -40°C; nitrosylation; 0.0833333 h;

in neat (no solvent) addn. of NOCl to AgCN (cooled to -40°C) in a bulb, vigorously stirring, keeping the react.vessel cold (dry ice/acetone bath, -30°C); procedure according to literature method; after 15-20 min the gaseous products are trapped out into a seperate bulb immersed in liquid N2, repeated bulb to bulb distrbu. from a hexane-liquid N2 slush bath;

Kinetics; photolysis;

Irradiation;

Irradiation (UV/VIS);

Kinetics; laser pump technique, 298-740K, pressure (Ar or N2 buffer gas) 30-500 Torr;

nitrosyl chloride -70 deg C -> -25 deg C;

in neat (no solvent, gas phase) Kinetics; at 704-1659 K;

photolysis;