3-(三甲基硅烷基)-3-丁烯-2-酮合成路线 （共 13 条）
反应条件
potassium hydroxide; ammonia; lithium; tert-butyl alcohol Yield given. Multistep reaction;
参考文献
Paquette, Leo A.; Sauer, Daryl R.; Cleary, Darryl G.; Kinsella, Mary A.; Blackwell, Christopher M.; Anderson, Lawrence G.
Journal of the American Chemical Society, 1992 , vol. 114, # 19 p. 7375 - 7387
反应条件
pyridine; 4-(N,N-dimethlyamino)pyridine; 5E-4 M TPP; oxygen; acetic anhydride in methyl acetate
T=-5°C; 4.5 h; Irradiationin a test tube;
参考文献
Adam; Richter
Synthesis, 1994 , # 2 p. 176 - 180
反应条件
3,3-dimethyldioxirane in dichloromethane; acetone
3.5 h; Ambient temperature;
参考文献
Adam, Waldemar; Prechtl, Frank; Richter, Markus J.; Smerz, Alexander K.
Tetrahedron Letters, 1995 , vol. 36, # 28 p. 4991 - 4994
反应条件
PhCH2Pd(PPh3)2Cl in benzene
24 h; Heating;
参考文献
Soderquist, John A.; Leong, William Wei-Hwa
Tetrahedron Letters, 1983 , vol. 24, # 23 p. 2361 - 2362
反应条件
chromium(VI) oxide in sulfuric acid
参考文献
Garratt, Peter J.; Tsotinis, Andrew
Tetrahedron Letters, 1986 , vol. 27, # 24 p. 2761 - 2762
反应条件
1: 1.) Mg
2: CrO3 / H2SO4
View Scheme
参考文献
Garratt, Peter J.; Tsotinis, Andrew
Tetrahedron Letters, 1986 , vol. 27, # 24 p. 2761 - 2762
反应条件
1: diethyl ether / 0.5 h / 0 °C
2: 4.7 g / pyridinium chlorochromate / CH2Cl2 / 2 h / Ambient temperature
View Scheme
参考文献
Okumoto, Hiroshi; Tsuji, Jiro
Synthetic Communications, 1982 , vol. 12, # 13 p. 1015 - 1020
反应条件
1: 8.93 g / p-toluenesulfonic acid, H2O / acetone / 1 h / Ambient temperature
2: diethyl ether / 0.5 h / 0 °C
3: 4.7 g / pyridinium chlorochromate / CH2Cl2 / 2 h / Ambient temperature
View Scheme
参考文献
Okumoto, Hiroshi; Tsuji, Jiro
Synthetic Communications, 1982 , vol. 12, # 13 p. 1015 - 1020
反应条件
titanium(IV) isopropylate; 4 A molecular sieve; oxygen; 5,15,10,20-tetraphenylporphyrin
1.) CH2Cl2, -10 to -5 deg C, irradiation, 6 h, 2.) 0 deg C, 6 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Adam, Waldemar; Richter, Markus J.
Journal of Organic Chemistry, 1994 , vol. 59, # 12 p. 3341 - 3346
反应条件
in tetrahydrofuran; diethyl ether
参考文献
Brook,A.G.; Duff,J.M.
Canadian Journal of Chemistry, 1973 , vol. 51, p. 2024 - 2032
