1: 1.) Na, 2.) sym-collidine, CuI / 2.) reflux, 14 h 2: 1.) t-BuLi / 1.) THF, from -70 deg C to 65 deg C, 45 min, 2.) THF, from -65 deg C to RT, 12 h View Scheme
参考文献
Bonhote, Pierre; Moser, Jacques-E.; Humphry-Baker, Robin; Vlachopoulos, Nicolas; Zakeeruddin, Shaik M.; Walder, Lorenz; Graetzel, Michael
Journal of the American Chemical Society, 1999 , vol. 121, # 6 p. 1324 - 1336
copper(l) iodide; sodium methylate in pyridine 2 h; Heating;
参考文献
Rhile, Ian J.; Markle, Todd F.; Nagao, Hirotaka; DiPasquale, Antonio G.; Lam, Oanh P.; Lockwood, Mark A.; Rotter, Katrina; Mayer, James M.
Journal of the American Chemical Society, 2006 , vol. 128, # 18 p. 6075 - 6088
Bonhote, Pierre; Moser, Jacques-E.; Humphry-Baker, Robin; Vlachopoulos, Nicolas; Zakeeruddin, Shaik M.; Walder, Lorenz; Graetzel, Michael
Journal of the American Chemical Society, 1999 , vol. 121, # 6 p. 1324 - 1336
Bonhote, Pierre; Moser, Jacques-E.; Humphry-Baker, Robin; Vlachopoulos, Nicolas; Zakeeruddin, Shaik M.; Walder, Lorenz; Graetzel, Michael
Journal of the American Chemical Society, 1999 , vol. 121, # 6 p. 1324 - 1336
1: tris(4-bromophenyl)amine With tert.-butyl lithium in diethyl ether; pentane T=-78°C; 1 h; Inert atmosphere; 2: N,N-dimethyl-formamide in diethyl ether; pentane 2 h; Inert atmosphere;
参考文献
Albrecht, Markus; Shang, Yuli; Rhyssen, Tanja; Stubenrauch, Jan; Winkler, Henrik D. F.; Schalley, Christoph A.
European Journal of Organic Chemistry, 2012 , # 12 p. 2422 - 2427
