2-氯-1,1,1,3,3,3-六氟丙烷合成路线 （共 35 条）
反应条件
1: With potassium acetate in N,N-dimethyl-formamide T=20°C; Inert atmosphere; 2: With ethanol; sulfuric acid
参考文献
SOLVAY SA; Braun, Max Josef; Kasubke, Michael
Patent: EP2626341 A1, 2013 ;
Location in patent: Paragraph 0086-0087 ;
反应条件
hydrogen fluoride; copper-substituted α-chromium oxide (99percent chromium/1percent copper) treated with HF
T=280°C; P=760.051 Torr; 0.00138889 h; Inert atmosphereMonel.(TM). nickel alloy tube packed with Monel.(TM). turnings;
参考文献
Rao, Velliyur Nott Mallikarjuna; Rosenfeld, H. David; Sievert, Allen; Subramoney, Shekhar
Patent: US2010/152503 A1, 2010 ;
Location in patent: Page/Page column 11 ;
反应条件
hydrogen fluoride; antimony(V) pentachloride
T=250°C;
参考文献
McBee; Truchan; Bolt
Journal of the American Chemical Society, 1948 , vol. 70, p. 2023
反应条件
hydrogen
T=100 - 500°C; P=735.572 - 6546.59 Torr; 0.000833333 - 0.00983333 h; Combinatorial reaction / High throughput screening (HTS);
参考文献
Hedrick, Vicki E.; Boggs, Janet K.; Brandstadter, Stephan M.; Cohn, Mitchel
Patent: US2005/38302 A1, 2005 ;
Location in patent: Page/Page column 3-14 ;
反应条件
1,4,7,10-tetraoxa-cyclododecane; lithium chloride in acetylacetone
T=130°C; 16 h;
参考文献
Hanack, Michael; Ullmann, Joerg
Journal of Organic Chemistry, 1989 , vol. 54, # 6 p. 1432 - 1435
反应条件
hydrogen fluoride
T=260°C; P=760.051 Torr; 0.00833333 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2005/37744 A1, 2005 ;
Location in patent: Page/Page column 13-14; 15 ;
反应条件
hydrogen fluoride; catalyst from comparative example 1 (100percent Cr)
T=300°C; P=760.051 Torr; 0.00138889 h; Gas phase; Product distribution / selectivity;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2007/19357 A1, 2007 ;
Location in patent: Page/Page column 12-14 ;
反应条件
hydrogen fluoride; chlorine; chromium cobalt oxide in nitrogen
T=300 - 400°C; P=760.051 Torr; 0.00416667 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2004/18397 A1, 2004 ;
Location in patent: Page 18; 24 ;
反应条件
hydrogen fluoride; Cr(NO3)3/ZnCl2 95/5 calcined at 900 C
T=320°C; P=760.051 Torr; 0.00416667 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2005/37744 A1, 2005 ;
Location in patent: Page/Page column 13-14; 15 ;
反应条件
hydrogen; 0.5 Pd/C
T=175 - 225°C; Gas phase;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2005/37743 A1, 2005 ;
Location in patent: Page/Page column 16; 19 ;
