1,1,1,2,3,3-六氟丙烷合成路线 (共 44 条)
反应条件
atomic oxygen radical T=26.9°C; ΔH (excit.); Rate constant;
参考文献
Morris, Robert A.; Viggiano, A. A.; Arnold, Susan T.; Paulson, J. F.; Liebman, Joel F.
Journal of Physical Chemistry, 1995 , vol. 99, # 16 p. 5992 - 5999
反应条件
potassium hydroxide in water T=155 - 170°C; 6 h; Product distribution / selectivity;
参考文献
Arkema France
Patent: US2011/190554 A1, 2011 ;
Location in patent: Page/Page column 4 ;
反应条件
T=400°C; 0.05 h; Gas phase; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: WO2009/84703 A1, 2009 ;
Location in patent: Page/Page column 22-23; 24 ;
反应条件
dioxygen ion T=26.9°C; ΔH (excit.); Rate constant;
参考文献
Morris, Robert A.; Viggiano, A. A.; Arnold, Susan T.; Paulson, J. F.; Liebman, Joel F.
Journal of Physical Chemistry, 1995 , vol. 99, # 16 p. 5992 - 5999
反应条件
O(1+) T=26.9°C; ΔH (excit.); Rate constant;
参考文献
Morris, Robert A.; Viggiano, A. A.; Arnold, Susan T.; Paulson, J. F.; Liebman, Joel F.
Journal of Physical Chemistry, 1995 , vol. 99, # 16 p. 5992 - 5999
反应条件
carbonaceous catalyst T=200 - 350°C; Gas phaseInert atmosphere; Product distribution / selectivity;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2009/105521 A1, 2009 ;
Location in patent: Page/Page column 39-40 ;
反应条件
pre-fluorinated 6percent Zn on chromia T=340°C; 0.0198694 - 0.118889 h; Product distribution / selectivity;
参考文献
INEOS FLUOR HOLDINGS LIMITED
Patent: WO2008/40969 A2, 2008 ;
Location in patent: Page/Page column 33-38 ;
反应条件
pre-fluorinated 6percent Zn on chromia T=340°C; 0.00363333 - 0.120956 h; Product distribution / selectivity;
参考文献
INEOS FLUOR HOLDINGS LIMITED
Patent: WO2008/40969 A2, 2008 ;
Location in patent: Page/Page column 33-36 ;
反应条件
pre-fluorinated 6percent Zn on chromia T=340°C; 0.0198694 - 0.118889 h; Product distribution / selectivity;
参考文献
INEOS FLUOR HOLDINGS LIMITED
Patent: WO2008/40969 A2, 2008 ;
Location in patent: Page/Page column 33-38 ;
反应条件
chlorine T=23°C; Photochlorination; P=760.051 Torr; 1 h; Irradiation with sunlamp; Product distribution / selectivity;
参考文献
Rao, Velliyur Nott Mallikarjuna; Sievert, Allen Capron
Patent: US2007/265368 A1, 2007 ;
Location in patent: Page/Page column 5 ;