6-甲基-1,2,3,4-四氢异喹啉合成路线 （共 6 条）
反应条件
[{(η5-C5Me5)RhCl}2(μ-Cl)2]; potassium iodide T=40°C; 24 h;
参考文献
BRISTOL-MYERS SQUIBB COMPANY; ORWAT, Michael J.; PINTO, Donald J.P.; SMITH II, Leon M.; SRIVASTAVA, Shefali; CORTE, James R.
Patent: WO2013/55984 A1, 2013 ;
Location in patent: Paragraph 00298 ;
反应条件
hydrogenchloride T=120°C;
参考文献
v. Braun; Blessing; Cahn
Chemische Berichte, 1924 , vol. 57, p. 910
Full Text Show Details
Riedel,J. D.
Patent: DE423027 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 15, p. 1712
反应条件
1: 2.) sodium borohydride, aq. sodium hydroxide, 3.) aq. HBr / 1) reflux, 2 h; 2) ethanol, below 20 deg C, 1 h; 3) reflux, 1 h 2: 87 percent / AlCl3 / decahydronaphthalene / 2 h / 180 °C View Scheme
参考文献
Peerzada
Synthetic Communications, 1997 , vol. 27, # 14 p. 2533 - 2538
反应条件
1: phosphorus pentachloride; aluminium chloride; nitrobenzene 2: concentrated hydrochloric acid / 120 °C View Scheme
参考文献
v. Braun; Blessing; Cahn
Chemische Berichte, 1924 , vol. 57, p. 910
Full Text Show Details
Riedel,J. D.
Patent: DE423027 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 15, p. 1712
反应条件
1: NaOH-solution 2: phosphorus pentachloride; aluminium chloride; nitrobenzene 3: concentrated hydrochloric acid / 120 °C View Scheme
参考文献
v. Braun; Blessing; Cahn
Chemische Berichte, 1924 , vol. 57, p. 910
反应条件
manganese(IV) oxide in dichloromethane
4 h;
参考文献
BRISTOL-MYERS SQUIBB COMPANY; ORWAT, Michael J.; PINTO, Donald J.P.; SMITH II, Leon M.; SRIVASTAVA, Shefali; CORTE, James R.
Patent: WO2013/55984 A1, 2013 ;
Location in patent: Paragraph 00299 ;
