1-苯基-4-戊烯-1-炔合成路线 （共 44 条）
反应条件
bis(acetylacetonate)nickel(II); diisobutylaluminium hydride in tetrahydrofuran; toluene
1 h; Heating;
参考文献
Ikeda, Shin-ichi; Cui, Dong-Mei; Sato, Yoshiro
Journal of Organic Chemistry, 1994 , vol. 59, # 23 p. 6877 - 6878
反应条件
1: With bis-triphenylphosphine-palladium(II) chloride; triethylamine
T=20°C; Sonogashira coupling; 0.0833333 h; Inert atmosphere;
2: With copper(l) iodide
Sonogashira coupling; Inert atmosphere;
参考文献
Briones, John F.; Davies, Huw M. L.
Organic Letters, 2011 , vol. 13, # 15 p. 3984 - 3987
反应条件
lt;η3-C3H5Pd(PPh3)2gt;+*Cl- in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 4 h;
参考文献
Bumagin, N. A.; Kasatkin, A. N.; Beletskaya, I. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 4 p. 828 - 833
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 4 p. 912 - 918
反应条件
potassium fluoride; copper(l) iodide in N,N-dimethyl-formamide
T=80°C; 20 h;
参考文献
Stadnichuk, M. D.; Aleksandrova, E. A.
Russian Journal of General Chemistry, 1993 , vol. 63, # 10.2 p. 1662
Zhurnal Obshchei Khimii, 1993 , vol. 63, # 10 p. 2395 - 2396
反应条件
1: 2,6-lutidine / CH2Cl2 / 0 - 20 °C
2: 2N NaOH / tetrahydrofuran / 1 h / 20 °C
3: 79 percent / toluene; tetrahydrofuran / -45 - 20 °C
View Scheme
参考文献
Katritzky, Alan R.; Abdel-Fattah, Ashraf A. A.; Wang, Mingyi
Journal of Organic Chemistry, 2002 , vol. 67, # 21 p. 7526 - 7529
反应条件
1: 2N NaOH / tetrahydrofuran / 1 h / 20 °C
2: 79 percent / toluene; tetrahydrofuran / -45 - 20 °C
View Scheme
参考文献
Katritzky, Alan R.; Abdel-Fattah, Ashraf A. A.; Wang, Mingyi
Journal of Organic Chemistry, 2002 , vol. 67, # 21 p. 7526 - 7529
反应条件
tetrakis(triphenylphosphine) palladium(0) in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 6 h;
参考文献
Bumagin, N. A.; Kasatkin, A. N.; Beletskaya, I. P.
Doklady Chemistry, 1982 , vol. 266, p. 345 - 348
Dokl. Akad. Nauk SSSR Ser. Khim., 1982 , vol. 266, # 4 p. 862 - 866
反应条件
lt;η3-C3H5Pd(PPh3)2gt;+*Cl- in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 4 h;
参考文献
Bumagin, N. A.; Kasatkin, A. N.; Beletskaya, I. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 4 p. 828 - 833
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 4 p. 912 - 918
反应条件
tetrakis(triphenylphosphine) palladium(0) in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 6 h;
参考文献
Bumagin, N. A.; Kasatkin, A. N.; Beletskaya, I. P.
Doklady Chemistry, 1982 , vol. 266, p. 345 - 348
Dokl. Akad. Nauk SSSR Ser. Khim., 1982 , vol. 266, # 4 p. 862 - 866
反应条件
lt;η3-C3H5Pd(PPh3)2gt;+*Cl- in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 4 h;
参考文献
Bumagin, N. A.; Kasatkin, A. N.; Beletskaya, I. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 4 p. 828 - 833
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 4 p. 912 - 918
