1,2-双(4-氯苯基)-2-羟基乙酮合成路线 （共 62 条）
反应条件
phosphoric acid; N-hexadecyl-N,N,N-trimethylammonium bromide; N-hexadecylthiazolium bromide; 3-methyltetra-acetylriboflavin
T=30°C; 24 h; pH 8.0; Yields of byproduct given;
参考文献
Shinkai, Seiji; Yamashita, Takaharu; Kusano, Yumiko; Manabe, Osamu
Tetrahedron Letters, 1980 , vol. 21, p. 2543 - 2546
反应条件
N-hexadecyl-N,N,N-trimethylammonium bromide
T=30°C; 24 h; pH 8.0 with 0.05 M phosphate; Mechanism;
参考文献
Shinkai, Seiji; Yamashita, Takaharu; Kusano, Yumiko; Manabe, Osamu
Tetrahedron Letters, 1980 , vol. 21, p. 2543 - 2546
反应条件
potassium phosphate; (S)-5-benzhydryl-2-(2,6-dimethoxyphenyl)-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium tetrafluoroborate in toluene
T=20°C; Stetter 1,4-Dicarbonyl Synthesis; Inert atmosphereSchlenk technique; Catalytic behavior; Reagent/catalystTime; enantioselective reaction;
参考文献
Wurz, Nathalie E.; Daniliuc, Constantin G.; Glorius, Frank
Chemistry - A European Journal, 2012 , vol. 18, # 51 p. 16297 - 16301
反应条件
sodium carbonate in dichloromethane
T=15°C; electrolysis; further materials of cathode; Product distributionMechanism;
参考文献
Brinkhaus, Karl-Heinz Grosse; Steckham, Eberhard; Schmidt, Werner
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1983 , vol. 37, # 6 p. 499 - 508
反应条件
sodium carbonate in dichloromethane
T=15°C; electrolysis; further materials of cathode; Product distributionMechanism;
参考文献
Brinkhaus, Karl-Heinz Grosse; Steckham, Eberhard; Schmidt, Werner
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1983 , vol. 37, # 6 p. 499 - 508
参考文献
Gomberg; Bachmann
Journal of the American Chemical Society, 1930 , vol. 52, p. 4967,4972
参考文献
Gomberg; van Natta
Journal of the American Chemical Society, 1929 , vol. 51, p. 2243
反应条件
anschliessendes Behandeln mit Eis und wss. Essigsaeure;
参考文献
Bachmann
Journal of the American Chemical Society, 1931 , vol. 53, p. 2758,2761, 2762
参考文献
Hantzsch; Glower
Chemische Berichte, 1907 , vol. 40, p. 1519
反应条件
1: (i) NH4NO3, Cu(OAc)2, (ii) N2H4*H2O, dioxane
2: HgO
View Scheme
参考文献
Braye,E.H.; Huebel,W.
Journal of Organometallic Chemistry, 1965 , vol. 3, p. 38 - 42
