1,2-双(4-氯苯基)-2-羟基乙酮合成路线 (共 62 条)
反应条件
1: 86 percent / DBU / dimethylformamide 2: 87 percent / KCN / dimethylformamide / 1 h / 80 °C View Scheme
参考文献
Miyashita; Suzuki; Okumura; Higashino
Chemical and Pharmaceutical Bulletin, 1996 , vol. 44, # 1 p. 252 - 254
反应条件
oxygen; sodium hydride in tetrahydrofuran T=20°C; 0.166667 h;
参考文献
Kim, Mi Jin; Yang, Jung Woon
Bulletin of the Korean Chemical Society, 2012 , vol. 33, # 9 p. 3122 - 3124
反应条件
in butan-1-ol Reflux;
参考文献
Assadieskandar, Amir; Amini, Mohsen; Salehi, Marjan; Sadeghian, Hamid; Alimardani, Maliheh; Sakhteman, Amirhossein; Nadri, Hamid; Shafiee, Abbas
Bioorganic and Medicinal Chemistry, 2012 , vol. 20, # 24 p. 7160 - 7166
反应条件
in N,N-dimethyl-formamide 6 h; Heating;
参考文献
Harris, Neil V.; Smith, Christopher; Asthon, Michael J.; Bridge, Andrew W.; Bush, Raymond C.; et al.
Journal of Medicinal Chemistry, 1992 , vol. 35, # 23 p. 4384 - 4392
反应条件
oxygen; VOCl3 in acetonitrile T=20°C; Oxidation; 1.5 h;
参考文献
Kirihara, Masayuki; Ochiai, Yuta; Takizawa, Shinobu; Takahata, Hiroki; Nemoto, Hideo
Chemical Communications, 1999 , # 15 p. 1387 - 1388
反应条件
2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; oxygen; copper(II) bis(trifluoromethanesulfonate); (R)-(+)-1,1'-binaphthyl-2,2'-diamine in toluene T=60°C; 0.5 h; optical yield given as percent eeenantioselective reaction;
参考文献
Chemistry - A European Journal, , vol. 15, # 5 p. 1086 - 1090
反应条件
lt;Fe4S4gt;(tipbt)4gt;2- in N,N-dimethyl-formamide T=15°C; 1 h; various catalysts and solvents; Rate constantMechanism;
参考文献
Sugawara, Takashi; Ueyama, Norikazu; Nakamura, Akira
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1991 , # 2 p. 249 - 253
参考文献
Hantzsch; Glower
Chemische Berichte, 1907 , vol. 40, p. 1519
反应条件
lt;Fe4S4gt;(tipbt)4gt;2- in N,N-dimethyl-formamide T=15°C; 1 h; various catalysts and solvents; Rate constantMechanism;
参考文献
Sugawara, Takashi; Ueyama, Norikazu; Nakamura, Akira
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1991 , # 2 p. 249 - 253
反应条件
1: 1) HCl, 2) TsOH / 1) MeOH, 20-30 deg C, 2) Ac2O, 45 min, 160 deg C 2: 15 percent / O2 / tetraphenylporphine / CH2Cl2 / 2.5 h / -78 °C / Irradiation 3: toluene / 101.5 °C / mechanism, chemiluminescence, var. temp., ΔH(excit.), ΔS(excit.), ΔG(excit.), ΦT, ΦS View Scheme
参考文献
Adam, Waldemar; Platsch, Herbert; Schmidt, Ernst
Chemische Berichte, 1985 , vol. 118, # 11 p. 4385 - 4403