(丁烷-2-基-苯基-磷酰)苯合成路线 （共 8 条）
反应条件
1: P-diphenyl(N-benzyl-N-methyl)-λ5-phosphinamide; sec.-butyllithium With N,N'-dimethyl-N,N'-propyleneurea in tetrahydrofuran; cyclohexane
T=-90°C; 12 h;
2: benzyl bromide in tetrahydrofuran; cyclohexane
T=-90°C; 2 h;
参考文献
Fernandez, Ignacio; Forcen-Acebal, Angela; Garcia-Granda, Santiago; Lopez-Ortiz, Fernando
Journal of Organic Chemistry, 2003 , vol. 68, # 11 p. 4472 - 4485
反应条件
diphosphorous tetraiodide in carbon disulfide
24 h; Ambient temperature;
参考文献
Yamashita, Mitsuji; Tsunekawa, Kenji; Sugiura, Motoyuki; Oshikawa, Tatsuo; Inokawa, Saburo
Chemistry Letters, 1983 , p. 1673 - 1674
反应条件
in tetrahydrofuran
T=-20°C; Alkylation; 14 h;
参考文献
Dalpozzo, Renato; De Nino, Antonio; Miele, Daniela; Tagarelli, Antonio; Bartoli, Giuseppe
European Journal of Organic Chemistry, 1999 , # 9 p. 2299 - 2301
反应条件
aluminium trichloride; water
1.) 18-20 deg C, 1 day; 2.) 0 deg C; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Chauzov, V. A.; Studnev, Yu. N.; Rudnitskaya, L. S.; Fokin, A. V.
J. Gen. Chem. USSR (Engl. Transl.), 1989 , vol. 59, # 5.1 p. 1050 - 1055,928 - 931
反应条件
aluminium trichloride; water
1.) 0.5 h; 2.) 0 deg C; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Chauzov, V. A.; Studnev, Yu. N.; Rudnitskaya, L. S.; Fokin, A. V.
J. Gen. Chem. USSR (Engl. Transl.), 1989 , vol. 59, # 5.1 p. 1050 - 1055,928 - 931
反应条件
(i) SOCl2, toluene, (ii) /BRN= 4123272/, benzene; Multistep reaction;
参考文献
Davidson,A.H. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1977 , p. 550 - 565
反应条件
(i) nBuLi, Et2O, (ii) /BRN= 505934/; Multistep reaction;
参考文献
Davidson,A.H. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1977 , p. 550 - 565
反应条件
aluminium trichloride
T=18 - 20°C; 24 h; followed by hydrolysis with H2O at 0 deg C; other temperatures and times, and other butyl halides investigated; MechanismProduct distribution;
参考文献
Chauzov, V. A.; Studnev, Yu. N.; Rudnitskaya, L. S.; Fokin, A. V.
J. Gen. Chem. USSR (Engl. Transl.), 1989 , vol. 59, # 5.1 p. 1050 - 1055,928 - 931
