(3,3-二甲基-1-丁炔)-苯合成路线 （共 61 条）
反应条件
tetrakis(triphenylphosphine) palladium(0)
参考文献
Klusener; Hanekamp; Brandsma; Von Rague Schleyer
Journal of Organic Chemistry, 1990 , vol. 55, # 4 p. 1311 - 1321
反应条件
(tBuO)3W≡CC(CH3)3 in toluene
T=25°C; estimated rate and time of equilibrium (4 h);
参考文献
Wengrovius,J.H.; Sancho,J.; Schrock,R.R.
Journal of the American Chemical Society, 1981 , vol. 103, p. 3932
反应条件
W(CCMe3)(O=PEt2)Cl3 in toluene
T=70°C; 1 h; Product distribution;
参考文献
Wengrovius,J.H.; Sancho,J.; Schrock,R.R.
Journal of the American Chemical Society, 1981 , vol. 103, p. 3932
反应条件
(i) EtMgBr, (ii) /BRN= 1730892/; Multistep reaction;
参考文献
Zimmerman,H.E.; Pincock,J.A.
Journal of the American Chemical Society, 1973 , vol. 95, # 10 p. 3246 - 3250
Full Text View citing articles Show Details
Yates,K.; McDonald,R.S.
Journal of Organic Chemistry, 1973 , vol. 38, # 14 p. 2465 - 2478
反应条件
in benzene
byproducts: Bu3SnCl; Irradiation (UV/VIS); mixt. of substrate and mercurial is irradiated in nitrogen-purged solvent in Pyrex tube with 350-nm Rayonet photoreactor for 24 h; GLC, (1)H-NMR, GCMS;
参考文献
Russell, Glen A.; Ngoviwatchai, Preecha; Tashtoush, Hasan I.
Organometallics, 1988 , vol. 7, p. 696 - 702
反应条件
in benzene
Kinetics; Irradiation (UV/VIS); substrate and mercurial is irradiated in nitrogen-purged solvent in Pyrex tube with 350-nm Rayonet photoreactor for 24 h; GLC, 1H-NMR, GCMS;
参考文献
Russell, Glen A.; Ngoviwatchai, Preecha; Tashtoush, Hasan I.
Organometallics, 1988 , vol. 7, p. 696 - 702
反应条件
(tBuO)3W≡CC(CH3)3 in toluene
T=25°C; estimated rate and time of equilibrium (1 h);
参考文献
Wengrovius,J.H.; Sancho,J.; Schrock,R.R.
Journal of the American Chemical Society, 1981 , vol. 103, p. 3932
反应条件
1: LiAlH4 / diethyl ether / 1) 0 deg C, 20 min, 2) r.t., 1 h
2: 58 percent / 200 °C / 0 Torr
View Scheme
参考文献
Heydt, Heinrich; Ehle, Michael; Haber, Steffen; Hoffmann, Juergen; Wagner, Oliver; Goeller, Andreas; Clark, Timothy; Regitz, Manfred
Chemische Berichte, 1997 , vol. 130, # 6 p. 711 - 723
反应条件
1: 85 percent / CaCl2, CuCl, Cu, 12N HCl / diethyl ether; petroleum ether / 1 h / 5 °C
2: 1.) Mg / 1.) Et2O; 2.) 12 h, RT; 2 h, reflux
View Scheme
参考文献
Mesnard, Danielle; Bernadou, Francoise; Miginiac, Leone
Journal of Chemical Research, Miniprint, 1981 , # 9 p. 3216 - 3245
反应条件
2: aq. K2SO4
3: (pyrolysis)
View Scheme
参考文献
Truce,W.E.; Wolf,G.C.
Journal of Organic Chemistry, 1971 , vol. 36, # 13 p. 1727 - 1732
