1,2-双(苯基)-1,1,2,2-四氟乙烷合成路线 （共 13 条）
反应条件
ethanol; [bis(2-methoxyethyl)amino]-sulfur trifluoride in dichloromethane
T=60°C; 24 h;
参考文献
Singh; Majumder; Shreeve
Journal of Organic Chemistry, 2001 , vol. 66, # 19 p. 6263 - 6267
反应条件
pyridinium polyhydrogen fluoride; NOBF4 in dichloromethane
24 h; Ambient temperature;
参考文献
Gatenyo, Julia; Rozen, Shlomo
Journal of Fluorine Chemistry, 2009 , vol. 130, # 3 p. 332 - 335
反应条件
fluorine in monofluoro-trichloromethane
T=-78°C;
参考文献
Mcewen,W.E.; Guzikowski,A.P.
Journal of Fluorine Chemistry, 1984 , vol. 25, p. 169
反应条件
iodine monofluoride in chloroform; monofluoro-trichloromethane
T=-75°C; 0.0833333 h;
参考文献
Rozen, Shlomo; Brand, Michael
Journal of Organic Chemistry, 1986 , vol. 51, # 2 p. 222 - 225
反应条件
1: 1.) NaNO2, aq. HCl / 1.) -10 to -15 deg C, 2.) H2O, acetone, 10-15 deg C, 2 h
2: 92 percent / Cu, pyridine / 2 h / 100 °C
3: 82 percent / perbenzoic acid / CH2Cl2 / 16 h / 25 °C
4: 73 percent / SF4 / CH2Cl2 / 1.) 40 deg C, 2 h, 2.) 60 deg C, 3 h
View Scheme
参考文献
Kremlev, M. M.; Maznyi, I. S.; Sereda, S. V.; Yagupol'skii, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1992 , vol. 28, # 5.1 p. 758 - 761
Zhurnal Organicheskoi Khimii, 1992 , vol. 28, # 5 p. 982 - 986
反应条件
1: 92 percent / Cu, pyridine / 2 h / 100 °C
2: 82 percent / perbenzoic acid / CH2Cl2 / 16 h / 25 °C
3: 73 percent / SF4 / CH2Cl2 / 1.) 40 deg C, 2 h, 2.) 60 deg C, 3 h
View Scheme
参考文献
Kremlev, M. M.; Maznyi, I. S.; Sereda, S. V.; Yagupol'skii, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1992 , vol. 28, # 5.1 p. 758 - 761
Zhurnal Organicheskoi Khimii, 1992 , vol. 28, # 5 p. 982 - 986
反应条件
1: 1.) NaNO2, aq. HCl / 1.) -10 to -15 deg C, 2.) H2O, acetone, 10-15 deg C, 2 h
2: 92 percent / Cu, pyridine / 2 h / 100 °C
3: 82 percent / perbenzoic acid / CH2Cl2 / 16 h / 25 °C
4: 73 percent / SF4 / CH2Cl2 / 1.) 40 deg C, 2 h, 2.) 60 deg C, 3 h
View Scheme
参考文献
Kremlev, M. M.; Maznyi, I. S.; Sereda, S. V.; Yagupol'skii, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1992 , vol. 28, # 5.1 p. 758 - 761
Zhurnal Organicheskoi Khimii, 1992 , vol. 28, # 5 p. 982 - 986
反应条件
XeF2; hydrogen fluoride
参考文献
Gregorcic,A.; Zupan,M.
Journal of Organic Chemistry, 1979 , vol. 44, # 8 p. 1255 - 1258
反应条件
1: XeF2, HF
2: KOtBu
3: XeF2, HF
View Scheme
参考文献
Gregorcic,A.; Zupan,M.
Journal of Organic Chemistry, 1979 , vol. 44, # 8 p. 1255 - 1258
反应条件
1: KOtBu
2: XeF2, HF
View Scheme
参考文献
Gregorcic,A.; Zupan,M.
Journal of Organic Chemistry, 1979 , vol. 44, # 8 p. 1255 - 1258
