trichlorophosphate in toluene 1 h; Heating;

1: NaBH4, CoCl2 / methanol / 0.5 h / 0 °C 2: pyridine / 1 h / Ambient temperature 3: 94 mg / POCl3 / toluene / 1 h / Heating View Scheme

1: 57 percent / chloranil / xylene / 2 h / Heating 2: NaBH4, CoCl2 / methanol / 0.5 h / 0 °C 3: pyridine / 1 h / Ambient temperature 4: 94 mg / POCl3 / toluene / 1 h / Heating View Scheme

1: 1) lithium diisopropylamide / 1) THF, -78 deg C, 1 h, 2) -78 deg C, 30 min 2: 90 percent / Na(Hg), Na2HPO4 / methanol; tetrahydrofuran / 4 h / 25 °C 3: 57 percent / chloranil / xylene / 2 h / Heating 4: NaBH4, CoCl2 / methanol / 0.5 h / 0 °C 5: pyridine / 1 h / Ambient temperature 6: 94 mg / POCl3 / toluene / 1 h / Heating View Scheme

1: 90 percent / Na(Hg), Na2HPO4 / methanol; tetrahydrofuran / 4 h / 25 °C 2: 57 percent / chloranil / xylene / 2 h / Heating 3: NaBH4, CoCl2 / methanol / 0.5 h / 0 °C 4: pyridine / 1 h / Ambient temperature 5: 94 mg / POCl3 / toluene / 1 h / Heating View Scheme

1: pyridine / 1 h / Ambient temperature 2: 94 mg / POCl3 / toluene / 1 h / Heating View Scheme

暂无反应条件数据

palladium on activated charcoal in decalin 1.5 h; Heating;