(S)-(+)-2-丁醇合成路线 （共 56 条）
反应条件
methyl-isobutyl-carbinol; carbonyl reductase; nicotinamide adenine dinucleotide in water T=30°C; pH=7.0; Buffer (100mM TEA); Product distribution / selectivity;
参考文献
IEP GMBH
Patent: US2007/265477 A1, 2007 ;
Location in patent: Page/Page column 3 ;
反应条件
hydrogen; 10percentPd/C; 1,2-diaminoethane; mixture of T=25°C; P=37503.8 Torr; 24 h; Conversion of starting material;
参考文献
Schlummer, Bjorn; Sturmann, Martin
Patent: US2005/54736 A1, 2005 ;
Location in patent: Page/Page column 3; 4 ;
反应条件
hydrogen; palladium 10 on activated carbon; N-butylamine in water T=30°C; 30 h;
参考文献
DAISO CO., LTD.
Patent: EP1582511 A2, 2005 ;
Location in patent: Page/Page column 5 ;
反应条件
(R,R)-C6H12BH2(1-)*Li(1+)*OEt2; methyl iodide in diethyl ether T=4°C; 36 h;
参考文献
Masamune, Satoru; Kim, ByeongMoon; Petersen, John S.; Sato, Tsuneo; Veenstra, Siem J.; Imai, Toshiro
Journal of the American Chemical Society, 1985 , vol. 107, # 15 p. 4549 - 4551
反应条件
(R,R)-C6H12BH2(1-)*Li(1+)*OEt2; methyl iodide in diethyl ether T=-20°C; 12 h;
参考文献
Masamune, Satoru; Kim, ByeongMoon; Petersen, John S.; Sato, Tsuneo; Veenstra, Siem J.; Imai, Toshiro
Journal of the American Chemical Society, 1985 , vol. 107, # 15 p. 4549 - 4551
反应条件
NB-Enantride in tetrahydrofuran; diethyl ether T=-100°C; 3 h; other ketones; Product distribution;
参考文献
Pham, Van T.; Phillips, Robert S.; Ljungdahl, Lars G.
Journal of the American Chemical Society, 1989 , vol. 111, # 5 p. 1935 - 1936
反应条件
phosphate buffer; glyceryl tributyrate 40 h; Ambient temperature;
参考文献
Cambou, Bernard; Klibanov, Alexander M.
Journal of the American Chemical Society, 1984 , vol. 106, # 9 p. 2687 - 2692
反应条件
biphenyl-2,2'-dicarboxylic acid; (1R,2R)-(+)-1,2-diphenylethylenediamine in ethanol Title compound not separated from byproducts;
参考文献
Liu, Taifeng; Liu, Yan; Xuan, Weimin; Cui, Yong
Angewandte Chemie - International Edition, 2010 , vol. 49, # 24 p. 4121 - 4124
反应条件
sodium hydroxide; diisopinocamphenylboron chloride; dihydrogen peroxide Yield given. Multistep reaction;
参考文献
Dhokte, Ulhas P.; Brown, Herbert C.
Tetrahedron Letters, 1996 , vol. 37, # 50 p. 9021 - 9024
反应条件
phosphate buffer; D-glucose; Synechococcus sp. PCC 7942; Triton X-100 in water T=25°C; pH=7.0; 72 h; Irradiation; Title compound not separated from byproducts;
参考文献
Shimoda, Kei; Kubota, Naoji; Hamada, Hiroki; Yamane, Shin-Ya; Hirata, Toshifumi
Bulletin of the Chemical Society of Japan, 2004 , vol. 77, # 12 p. 2269 - 2272
