1-氯-1,1,2,2,3,3,3-七氟丙烷合成路线 （共 23 条）
反应条件
fluorine
T=-30 - 0°C; Irradiationsteady-state flow process; the hydrocarbon vapor is condensed onto a NaF preaerosol and then subjected to attack by an excess of elemental F in He at first in the dark, then under UV irradiation; MechanismProduct distribution;
参考文献
Adcock, James L.; Evans, William D.
Journal of Organic Chemistry, 1984 , vol. 49, # 15 p. 2719 - 2723
反应条件
hydrogen fluoride; hydrogen; fluorided Pd on Al2O3
T=350°C; Product distribution / selectivity;
参考文献
E.I.DU PONT DE NEMOURS AND COMPANY
Patent: WO2008/54780 A2, 2008 ;
Location in patent: Page/Page column 20-21 ;
反应条件
byproducts: C3F7H; 8 h at 105°C.;
参考文献
Huested, D. R.; Kohlhase, W. L.
Journal of the American Chemical Society, 1954 , vol. 76, p. 5141 - 5144
反应条件
hydrogen fluoride; hydrogen; fluorided Pd on Al2O3
T=350°C; Product distribution / selectivity;
参考文献
E.I.DU PONT DE NEMOURS AND COMPANY
Patent: WO2008/54780 A2, 2008 ;
Location in patent: Page/Page column 21 ;
参考文献
Kinetic Chem.Inc.
Patent: US2490764 , 1945 ;
反应条件
bromine trifluoride
T=-80°C;
参考文献
Haszeldine; Steele
Journal of the Chemical Society, 1953 , p. 1592,1597
反应条件
fluorine
T=-30 - 0°C; Irradiationsteady-state flow process; the hydrocarbon vapor is condensed onto a NaF preaerosol and then subjected to attack by an excess of elemental F in He at first in the dark, then under UV irradiation; MechanismProduct distribution;
参考文献
Adcock, James L.; Evans, William D.
Journal of Organic Chemistry, 1984 , vol. 49, # 15 p. 2719 - 2723
参考文献
Harris,J.F.
Journal of Organic Chemistry, 1965 , vol. 30, p. 2182 - 2190
反应条件
135°C (16 h); pyrolysis;
参考文献
Prons, V. N.; Grinblat, M. P.; Klebanskii, L.
Zhurnal Obshchei Khimii, 1970 , vol. 40, p. 559 - 564
Zhurnal Obshchei Khimii, 1970 , vol. 40, p. 589 - 594
C.A., 1970 , vol. 73, p. 25595
参考文献
Emeleus,H.J.; Welcman,N.
Journal of the Chemical Society, 1963 , p. 1268 - 1271
