1,5-二甲基-1,4-环己二烯合成路线 (共 15 条)
反应条件
2,3-dicyano-5,6-dichloro-p-benzoquinone in acetic acid T=25°C; Rate constantMechanism;
参考文献
Thummel, Randolph P.; Cravey, Wesley E.; Cantu, David B.
Journal of Organic Chemistry, 1980 , vol. 45, # 9 p. 1633 - 1637
参考文献
Birch
Journal of the Chemical Society, 1947 , p. 1642,1647
参考文献
Journal of the Chemical Society, , p. 430,432, 433, 435
Journal of the Chemical Society, , p. 1642,1647
反应条件
C8H12*C26H24NPS*C32H12BF24(1-)*Ir(1+); hydrogen in dichloromethane P=15001.5 Torr; 18 h; optical yield given as percent destereoselective reaction;
参考文献
Paptchikhine, Alexander; Itto, Kaori; Andersson, Pher G.
Chemical Communications, 2011 , vol. 47, # 13 p. 3989 - 3991
反应条件
toluene-4-sulfonic acid; ozone in dichloromethane T=-78°C; Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 69, # 12 p. 4135 - 4139
反应条件
ethanol; ammonia; sodium
T=-78°C; 3 h;
参考文献
Last, Larry A.; Fretz, E. Robert; Coates, Robert M.
Journal of Organic Chemistry, 1982 , vol. 47, # 17 p. 3211 - 3219
反应条件
lithium; tert-butyl alcohol in ammonia
T=-78°C; 11 h;
参考文献
Gbara-Haj-Yahia, Isra; Zvilichovsky, Gury; Seri, Noa
Journal of Organic Chemistry, 2004 , vol. 69, # 12 p. 4135 - 4139
反应条件
white sand; calcium; tert-butyl alcohol in ethylenediamine
T=0°C; 24 h; Yield given. Yields of byproduct given;
参考文献
Benkeser, Robert A.; Laugal, James A.; Rappa, Angela
Tetrahedron Letters, 1984 , vol. 25, # 20 p. 2089 - 2092
反应条件
ammonia; sodium in methanol
T=-75 - -33°C; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Beger, J.; Thomas, B.; Vogel, T.; Kirmse, K.; Lang, R.
Journal fuer Praktische Chemie (Leipzig), 1991 , vol. 333, # 3 p. 481 - 488
反应条件
3-cyanobenzylnitrile; sodium tetrahydroborate in water; acetonitrile
8 h; Irradiation; Further byproducts given;
参考文献
Epling, Gary A.; Florio, Emily
Tetrahedron Letters, 1986 , vol. 27, # 13 p. 1469 - 1472