1: With Ind2TiMe2 in toluene T=80°C; P=760 Torr; 7 h; 2: With sodium cyanoborohydride; zinc(II) chloride in methanol; toluene T=25°C; 16 h;

lithium aluminium tetrahydride in diethyl ether Heating;

1: benzene 2: LiAlH4 / diethyl ether / Heating View Scheme

1: HCONH2, HCO2H / 180 °C 2: benzene 3: LiAlH4 / diethyl ether / Heating View Scheme

cycloocta-1,5-dienelt;(S)-1-(2-diphenylphosphino-1-naphthyl)isoquinolinegt;rhodium(I) trifluoromethanesulfonate; methyl-magnesium chloride; benzo[1,3,2]dioxaborole in tetrahydrofuran multistep reaction; other reagents, solvents; Product distribution;