1,1-二苯基-1,3-丁二烯合成路线 （共 34 条）
反应条件
1: cyclopropyl phenyl ketone (p-toluenesulfonyl)hydrazone With dichloro bis(acetonitrile) palladium(II); lithium tert-butylate; 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in 1,4-dioxane
0.0166667 h; Inert atmosphere;
2: bromobenzene in 1,4-dioxane
T=90°C; 2 h; Inert atmosphere; Reagent/catalystSolvent;
参考文献
Yang, Qin; Chai, Huining; Liu, Tingting; Yu, Zhengkun
Tetrahedron Letters, 2013 , vol. 54, # 48 p. 6485 - 6489
反应条件
NiCl2((PPh3)P)2 in benzene
Heating;
参考文献
Ng; Luh
Journal of the American Chemical Society, 1989 , vol. 111, # 25 p. 9119 - 9121
反应条件
bis(pentamethylcyclopentadienyl)titanium-ethylene complex in deuterated toluene
T=70°C; 1 h; sealed NMR tube;
参考文献
Mashima, Kazushi; Sakai, Nozomu; Takaya, Hidemasa
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 8 p. 2475 - 2483
反应条件
tris-(dibenzylideneacetone)dipalladium(0); lithium tert-butylate; 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in 1,4-dioxane
T=80°C; 12 h; Inert atmosphere;
参考文献
Zhou, Lei; Ye, Fei; Zhang, Yan; Wang, Jianbo
Organic Letters, 2012 , vol. 14, # 3 p. 922 - 925
反应条件
1: in tetrahydrofuran
T=20°C; 0.5 h; Inert atmosphere;
2: With phosphonic acid diethyl ester in tetrahydrofuran
T=20°C; Inert atmosphere;
参考文献
Wang, Tongqiang; Hu, Yuanyuan; Zhang, Songlin
Organic and Biomolecular Chemistry, 2010 , vol. 8, # 10 p. 2312 - 2315
反应条件
1: With phosphonic acid,diphenyl ester in tetrahydrofuran
T=20°C; 0.5 h; Inert atmosphere;
2: in tetrahydrofuran
T=50°C; 5 h; Inert atmosphere;
参考文献
Cui, Hua; Li, Ying; Zhang, Songlin
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 14 p. 2862 - 2869
反应条件
trichlorophosphate in pyridine
参考文献
Barltrop,J.A.; Carless,H.A.J.
Journal of the American Chemical Society, 1971 , vol. 93, p. 4794 - 4801
反应条件
2: TsOH, benzene-1,4-diol / benzene
View Scheme
参考文献
Eisch,J.J.; Husk,G.R.
Journal of Organic Chemistry, 1966 , vol. 31, p. 589 - 591
反应条件
bis(η3-allyl-μ-chloropalladium(II)); caesium carbonate; 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in acetonitrile
T=80°C; 4 h; Inert atmosphere;
参考文献
Zhou, Lei; Ye, Fei; Zhang, Yan; Wang, Jianbo
Organic Letters, 2012 , vol. 14, # 3 p. 922 - 925
反应条件
1: in tetrahydrofuran
T=20°C; 0.5 h; Inert atmosphere;
2: With phosphonic acid diethyl ester in tetrahydrofuran
Inert atmosphere;
参考文献
Li, Ying; Hu, Yuan-Yuan; Zhang, Song-Lin
Chemical Communications, 2013 , vol. 49, # 90 p. 10635 - 10637
