苯酚-2,3,4,5,6-d5合成路线 （共 12 条）
反应条件
10 platinum on carbon; water-d2 in cyclohexane; isopropyl alcohol T=80°C; 3 h; Inert atmosphere;
参考文献
Sawama, Yoshinari; Yamada, Tsuyoshi; Yabe, Yuki; Morita, Kosuke; Shibata, Kyoshiro; Shigetsura, Masahiro; Monguchi, Yasunari; Sajiki, Hironao
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 8 p. 1529 - 1534
反应条件
1: bromobenzene-d5 With copper(l) iodide; sodium iodide; N-methyl-2-(methylamino)ethylamine in 1,4-dioxane T=110°C; 6 h; Sealed tubeInert atmosphere; 2: cesium hydroxide monohydrate in 1,4-dioxane; water-d2 T=130°C; 24 h; Inert atmosphere;
参考文献
Liu, Weiping; Ackermann, Lutz
Organic Letters, 2013 , vol. 15, # 13 p. 3484 - 3486
反应条件
water-d2; BaO; Raney Ni-Al alloy T=60°C; 2 h; Irradiation;
参考文献
Mukumoto, Mamoru; Mashimo, Takuya; Tsuzuki, Hirohisa; Tsukinoki, Takehito; Uezu, Noriko; et al.
Journal of Chemical Research, Synopses, 1995 , # 10 p. 412 - 413
反应条件
Yield given. Multistep reaction;
参考文献
McCulla, Ryan D.; Jenks, William S.
Journal of the American Chemical Society, 2004 , vol. 126, # 49 p. 16058 - 16065
参考文献
Keresztury, Gabor; Billes, Ferenc; Kubinyi, Miklos; Sundius, Tom
Journal of Physical Chemistry A, 1998 , vol. 102, # 8 p. 1371 - 1380
反应条件
n-butyllithium; potassium tert-butylate 1) hexane, 3h; Yield given. Multistep reaction;
参考文献
Schlosser, Manfred; Choi, Jung Hoon; Takagishi, Sadahito
Tetrahedron, 1990 , vol. 46, # 16 p. 5633 - 5648
反应条件
triplet atomic oxygen O(3P) T=20.9°C; other temperatures, also in mixtures with benzene (molar ratios C6H6:C6D6, 0:1, 1:1 and 9:1); MechanismProduct distributionRate constant;
参考文献
Sol, Veronica M.; Louw, Robert; Mulder, Peter
Recueil des Travaux Chimiques des Pays-Bas, 1990 , vol. 109, p. 346 - 352
反应条件
Product distribution;
参考文献
Phung; Burton
Radiation Research, 1957 , vol. 7, p. 199,202
反应条件
bromine in 1,4-dioxane T=0°C;
参考文献
Shariatgorji, Mohammadreza; Nilsson, Anna; Goodwin, Richard J. A.; Svenningsson, Per; Schintu, Nicoletta; Banka, Zoltan; Kladni, Laszlo; Hasko, Tibor; Szabo, Andras; Andren, Per E.
Analytical Chemistry, 2012 , vol. 84, # 16 p. 7152 - 7157
反应条件
1.1: bromine / 1,4-dioxane / 0 °C 2.1: 1H-imidazole / N,N-dimethyl-formamide / 20 °C 3.1: n-butyllithium / tetrahydrofuran / -65 °C / |Inert atmosphere 3.2: 0 °C 4.1: hydrogenchloride / methanol / 20 °C / |Inert atmosphere View Scheme
参考文献
Shariatgorji, Mohammadreza; Nilsson, Anna; Goodwin, Richard J. A.; Svenningsson, Per; Schintu, Nicoletta; Banka, Zoltan; Kladni, Laszlo; Hasko, Tibor; Szabo, Andras; Andren, Per E.
Analytical Chemistry, 2012 , vol. 84, # 16 p. 7152 - 7157
