1-乙炔基-2,2,6-三甲基环己醇合成路线 （共 6 条）
反应条件
vanadium tri-n-propoxide; benzoic acid; hydroxytriphenylsilane in various solvent(s) T=140 - 150°C;
参考文献
Jalali-Naini, M.; Guillerm, D.; Lallemand, J-Y.
Tetrahedron, 1983 , vol. 39, # 5 p. 749 - 758
反应条件
titanium tetra-n-butoxide; 4-methyl-benzoic acid; copper(l) chloride in 1,2-dichloro-benzene T=130°C; 4 h; Title compound not separated from byproducts;
参考文献
Chabardes, Pierre
Tetrahedron Letters, 1988 , vol. 29, # 48 p. 6253 - 6256
反应条件
in tetrachloromethane (i) AIBN, (irradiation), (ii) CF3CO2H; Multistep reaction;
参考文献
Mantione,R.; Normant,H.
Bulletin de la Societe Chimique de France, 1973 , p. 2261 - 2265
反应条件
1: pyridine; trichlorophosphate / 20 - 120 °C / Inert atmosphere 2: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 4 h / 0 - 20 °C 3: pyridine 1-oxide; Cu(NCMe)4NTf2 / acetonitrile / 8 h / 80 °C View Scheme
参考文献
Gronnier, Colombe; Kramer, Soren; Odabachian, Yann; Gagosz, Fabien
Journal of the American Chemical Society, 2012 , vol. 134, # 2 p. 828 - 831
反应条件
1: pyridine; trichlorophosphate / 20 - 120 °C / Inert atmosphere 2: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 4 h / 0 - 20 °C 3: pyridine 1-oxide; Cu(NCMe)4NTf2 / acetonitrile / 8 h / 80 °C View Scheme
参考文献
Gronnier, Colombe; Kramer, Soren; Odabachian, Yann; Gagosz, Fabien
Journal of the American Chemical Society, 2012 , vol. 134, # 2 p. 828 - 831
反应条件
monoaluminum phosphate; pumice stone
T=270 - 290°C;
参考文献
Bhatia et al.
Journal of the Chemical Society, 1959 , p. 24,28
Full Text Show Details
Sobotka; Chanley
Journal of the American Chemical Society, 1949 , vol. 71, p. 4136,4138
