potassium phenolate 1.) DMF, 0 deg C; 2.) ether; various molar ratio of CO2 absorbed by PhOK to PhOK initially added, reaction time; Product distribution;
参考文献
Mori; Satake
Chemical and Pharmaceutical Bulletin, 1985 , vol. 33, # 8 p. 3469 - 3472
1: potassium tert-butylate / methanol / 23 - 60 °C 2: tetraethylammonium chloride; N,N-dimethyl-aniline; trichlorophosphate / acetonitrile / 0.33 h / 110 °C View Scheme
参考文献
Savall, Brad M.; Chavez, Frank; Tays, Kevin; Dunford, Paul J.; Cowden, Jeffery M.; Hack, Michael D.; Wolin, Ronald L.; Thurmond, Robin L.; Edwards, James P.
Journal of Medicinal Chemistry, 2014 , vol. 57, # 6 p. 2429 - 2439
1.1: 99 percent / 10-camphorsulfonic acid / methanol / 16 h / Heating 2.1: 92 percent / lithium diisopropylamide / tetrahydrofuran / 1 h / -40 °C 3.1: dimethyldioxirane / acetone; CH2Cl2 / 0.17 h 3.2: 70 percent / 10-camphorsulfonic acid / acetone / 0.5 h 4.1: 91 percent / imidazole; 4-dimethylaminopyridine / CH2Cl2 / 2 h / 20 °C 5.1: 100 percent / NaCl / dimethylsulfoxide; H2O / 0.5 h / 130 °C View Scheme
参考文献
Drew, Michael G. B.; Harwood, Laurence M.; Macias-Sanchez, Antonio J.; Scott, Richard; Thomas; Uguen, Daniel
Angewandte Chemie - International Edition, 2001 , vol. 40, # 12 p. 2311 - 2313
