in hexane
byproducts: LiCl; H2SiCl2 condensed into a suspn. of the Li-compd., mixt. warmed from -95°C to -25°C within 1.5 h; filtered, evapn. (vac.); not isolated; 1H-NMR;
参考文献
Haas, Alois; Hitze, Reiner; Krueger, Carl; Angermund, Klaus
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1984 , vol. 39, # 7 p. 890 - 896
in neat (no solvent)
byproducts: H2; reaction in presence of SbCl5 at room temperature;;
参考文献
Emeleus, H. J.; Maddock, A. G.
Journal of the Chemical Society, 1944 , p. 293 - 296
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Gmelin Handbook: Si: MVol.B, 233, page 635 - 638
in neat (no solvent)
fluorination of SiH2Cl2 with SbF3 at room temp. for a longer period of time;;
参考文献
Emeleus, H. J.; Maddock, A. G.
Journal of the Chemical Society, 1944 , p. 293 - 296
Full Text View citing articles Show Details
Gmelin Handbook: Si: MVol.B, 233, page 635 - 638
in neat (no solvent)
byproducts: H3SiCl, (H2SiS)3; compds. condensed into a vessel, reacted at 20°C for 21 days, ratio (H3Si)2S:H2SiCl2 = 2:1; fractional distn., chloro-product not analytically pure;
参考文献
Haas, Alois; Hitze, Reiner; Krueger, Carl; Angermund, Klaus
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1984 , vol. 39, # 7 p. 890 - 896
oxygen in gas
Kinetics; 26.5percent SiCl2H2+7percent SF6 or 22percent SiCl2H2+18percent SF6 in O2 reacted at room temp. and 2-5 Torr; reaction in flame detected by chemiluminescence spectra in near IR;
参考文献
Chernysh; Rubtsov; Tsvetkov
Kinetics and Catalysis, 2001 , vol. 42, # 5 p. 594 - 600
