3-烯丙基-4-羟基苯甲醛合成路线 （共 10 条）
反应条件
1: 89 percent / K2CO3 / acetone / 2 h / 60 °C 2: 82 percent / [RuClH(CO)(PPh3)3] / CH2Cl2 / 14 h / 65 °C 3: 50 percent / ((Mes)2C3H5N2)Cl2Ru=CHPh / toluene / 3 h / 90 °C View Scheme
参考文献
Van Otterlo, Willem A.L.; Morgans, Garreth L.; Madeley, Lee G.; Kuzvidza, Samuel; Moleele, Simon S.; Thornton, Natalie; De Koning, Charles B.
Tetrahedron, 2005 , vol. 61, # 32 p. 7746 - 7755
反应条件
potassium carbonate in acetone T=60°C; 2 h;
参考文献
Van Otterlo, Willem A.L.; Morgans, Garreth L.; Madeley, Lee G.; Kuzvidza, Samuel; Moleele, Simon S.; Thornton, Natalie; De Koning, Charles B.
Tetrahedron, 2005 , vol. 61, # 32 p. 7746 - 7755
反应条件
N,N-diethylaniline
T=190°C; 20 h;
参考文献
Liu, Zhiguo; Tang, Longguang; Zou, Peng; Zhang, Yali; Wang, Zhe; Fang, Qilu; Jiang, Lili; Chen, Gaozhi; Xu, Zheng; Zhang, Huajie; Liang, Guang
European Journal of Medicinal Chemistry, 2014 , vol. 74, p. 671 - 682
反应条件
T=200°C; Claisen rearrangement; 5 h;
参考文献
Gu, Wenxin; Silverman, Richard B
Organic letters, 2003 , vol. 5, # 4 p. 415 - 418
反应条件
hydrogenchloride; potassium hydrogencarbonate; N,N-diethylaniline in water; ethyl acetate; acetone
参考文献
Eli Lilly and Company
Patent: US5356917 A1, 1994 ;
反应条件
potassium carbonate in acetone
参考文献
Loctite (Ireland) Limited
Patent: US4640849 A1, 1987 ;
反应条件
1: 97 percent / K2CO3 / acetone / Heating
2: 86 percent / 5 h / 200 °C
View Scheme
参考文献
Gu, Wenxin; Silverman, Richard B
Organic letters, 2003 , vol. 5, # 4 p. 415 - 418
反应条件
T=185°C; Geschwindigkeitskonstante der Isomerisierung; Rate constant;
参考文献
Goering; Jacobson
Journal of the American Chemical Society, 1958 , vol. 80, p. 3277,3279
反应条件
potassium carbonate in acetone
T=20°C; 3 h;
参考文献
Liu, Zhiguo; Tang, Longguang; Zou, Peng; Zhang, Yali; Wang, Zhe; Fang, Qilu; Jiang, Lili; Chen, Gaozhi; Xu, Zheng; Zhang, Huajie; Liang, Guang
European Journal of Medicinal Chemistry, 2014 , vol. 74, p. 671 - 682
反应条件
potassium carbonate in acetone
参考文献
Loctite (Ireland) Limited
Patent: US4640849 A1, 1987 ;
