4-氯-2,3,5,6-四氟三氟甲基苯合成路线 （共 9 条）
反应条件
water; phosphorous acid trisdiethylamide in N,N-dimethyl-formamide T=20°C; protodechlorination; 0.5 h;
参考文献
Russian Chemical Bulletin, , vol. 46, # 4 p. 786 - 788
反应条件
1: 4-chloroheptafluorotoluene With zinc in N,N-dimethyl-formamide T=135°C; 4 h; 2: 3-chloroprop-1-ene With copper(l) chloride in N,N-dimethyl-formamide Further stages.;
参考文献
Russian Journal of Organic Chemistry, , vol. 44, # 1 p. 95 - 102
参考文献
Al-Saleh, Balkis A.; Banks, Ronald E.; Barlow, Michael G.
Journal of the Chemical Society, Chemical Communications, 1980 , # 21 p. 997 - 998
反应条件
chlorine
T=390 - 395°C; 0.266667 h;
参考文献
Platonov; Maksimov; Dvornikova; Nikul'shin
Russian Journal of Organic Chemistry, 2005 , vol. 41, # 11 p. 1647 - 1653
反应条件
chlorine trifluoride; boron trifluoride in ClSO2F (sulfuryl chloride fluoride)
T=-90 - -80°C; 0.416667 h;
参考文献
Bardin,V.V.; Furin,G.G.
Journal of Fluorine Chemistry, 1983 , vol. 23, p. 67
反应条件
1: 79 percent / 160 °C / 760 Torr
2: 92 percent / Cl2 / 550 °C
View Scheme
参考文献
Al-Saleh, Balkis A.; Banks, Ronald E.; Barlow, Michael G.
Journal of the Chemical Society, Chemical Communications, 1980 , # 21 p. 997 - 998
反应条件
T=550°C; P=1 Torr; Product distributionMechanism;
参考文献
Al-Saleh, Balkis A.; Banks, Ronald E.; Barlow, Michael G.
Journal of the Chemical Society, Chemical Communications, 1980 , # 21 p. 997 - 998
反应条件
hexaethylguanidinium chloride; sodium bromide
T=140 - 145°C; 7 h; Product distribution; Further Variations:Reagents;
参考文献
Shipilov; Zolotkova; Igumnov
Russian Journal of Organic Chemistry, 2004 , vol. 40, # 8 p. 1117 - 1120
反应条件
hexaethylguanidinium chloride; sodium chloride
T=140 - 145°C; 7 h; Product distribution; Further Variations:Reagents;
参考文献
Shipilov; Zolotkova; Igumnov
Russian Journal of Organic Chemistry, 2004 , vol. 40, # 8 p. 1117 - 1120
