3-亚甲基戊烷-1,5-二醇合成路线 （共 16 条）
反应条件
1,4-dioxane; nickel T=100°C; P=257428 Torr; Hydrogenation;
参考文献
Du Pont de Nemours and Co.
Patent: US2789996 , 1953 ;
反应条件
dinitrogen tetraoxide in nitric acid T=50°C; 2 h; Product distribution;
参考文献
Wilkes, John B.; Wall, Robert G.
Journal of Organic Chemistry, 1980 , vol. 45, # 2 p. 247 - 250
反应条件
dimethylaluminum chloride in dichloromethane
T=25°C; 1 h;
参考文献
Snider; Rodini; Kirk; Cordova
Journal of the American Chemical Society, 1982 , vol. 104, # 2 p. 555 - 563
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran
T=0 - 20°C; 3 h;
参考文献
Alonso, Francisco; Rodriguez-Fernandez, Mamen; Sanchez, Daniel; Yus, Miguel
European Journal of Organic Chemistry, 2011 , # 32 p. 6459 - 6469
反应条件
dimethylaluminum chloride in dichloromethane
T=25°C; 1 h;
参考文献
Snider; Rodini; Kirk; Cordova
Journal of the American Chemical Society, 1982 , vol. 104, # 2 p. 555 - 563
反应条件
methanol; sodium methylate
参考文献
Lehrich, Friedhelm; Hopf, Henning; Grunenberg, Joerg
European Journal of Organic Chemistry, 2011 , # 14 p. 2705 - 2718
参考文献
Blomquist; Verdol
Journal of the American Chemical Society, 1955 , vol. 77, p. 78
参考文献
Brace
Journal of the American Chemical Society, 1955 , vol. 77, p. 4666
反应条件
1: dimethylaluminum chloride / hexane; dichloromethane / 16 h / 0 - 20 °C / Inert atmosphere
2: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h / 0 - 20 °C
View Scheme
参考文献
Alonso, Francisco; Rodriguez-Fernandez, Mamen; Sanchez, Daniel; Yus, Miguel
European Journal of Organic Chemistry, 2011 , # 32 p. 6459 - 6469
反应条件
T=200°C; P=320 - 640 Torr;
参考文献
Brace
Journal of the American Chemical Society, 1955 , vol. 77, p. 4666
